With every moving day, the aspect that is going to be the most important for modern science and technology is the means to supply sufficient energy for all the scientific applications. As the resource of fossil fuel is draining out fast, an alternative is always required to satisfy the needs of the future world. Limited resources also force to innovate something that can utilise the resource more efficiently. This work is based on a simple synthesis route of biomass derived hard carbon and to exploring the possibility of using it as electrochemical supercapacitors. A cheap, eco-friendly and easily synthesized carbon material is utilized as electrode for electrochemical energy-storage. Four different hard carbons were synthesized from KOH activated banana stem (KHC), phosphoric acid treated banana stem derived carbons (PHC), corn-cob derived hard carbon (CHC) and potato starch derived hard carbons (SHC) and tested as supercapacitor electrodes. KOH-activated hard carbon has provided 479.23 F/g specific capacitance as calculated from its cycle voltammograms. A detailed analysis is done to correlate the results obtained with the material property. Overall, this work provides an in depth analysis of the science behind the components of an electrochemical energy-storage system as well as why the different characterization techniques are required to assess the quality and reliability of the material for electrochemical supercapacitor applications.
In
this study, we adopted a simple method to synthesize a graphene-like-structured
nanoporous carbon using a jute stick as a carbon precursor and studied
the electrochemical properties for supercapacitors. The synthesized
nanoporous carbon is composed of a graphene sheet-like network and
amorphous carbon, and the ratio between these two components is tuned
by the activation temperature. As the activation temperature is increased,
the amorphous carbon is converted into a stable graphene-like network
with a high specific surface area of 2396 m2/g, with a
graphene sheet-like morphology and a highly ordered graphitic sp2 carbon. For supercapacitor application, the nanoporous carbon
is studied in aqueous as well as organic electrolytes, and the material
shows excellent electrochemical performance in both the cases. It
exhibited a high specific capacitance of 282 F/g and shows excellent
rate capability with almost 70% capacitance retention at high current
rates. Furthermore, the assembled symmetric supercapacitor displays
a remarkable energy density of 20.6 W h kg–1 at
a high power density of 33 600 W kg–1, and
the benchmark studies revealed that the nanoporous carbon developed
in the present study is better than the commercially available supercapacitive
carbon (YP-50 F). A cylindrical supercapacitor device of capacitance
20 F with 2.7 V was fabricated using the nanoporous carbon electrode
and tested for running practical devices. The excellent electrochemical
performance of the electrode material can be attributed to the high
electrical conductivity of the ordered graphene network coupled with
high specific surface area and optimum pore size distribution of nanoporous
carbon. These results demonstrate a facile, low-cost, and eco-friendly
design of materials for energy storage applications.
Summary
Graphitic porous carbon sheets (GPCS), which were synthesized at a low temperature of 900°C by KOH chemical activation technique, possess a specific surface area of 1246 m2 g‐1 with high pore volume. The size of the pores varied in micro‐mesopore regions and exhibited three‐dimensional sheet‐like morphology composed of multilayered graphene sheets with an inter planar distance of 0.360 nm. The GPCS material was tested as anode for Li‐ion battery (LIB) application in half cell mode (vs Li+/Li). The fabricated GPCS electrode shows excellent electrochemical properties in comparison with commercial graphite such as a high discharge specific capacity of 1022 mA h g‐1 after 10 cycles at 100 mA g‐1 and excellent specific capacity retention of 170 mA h g‐1 at a very high current rate of 8000 mA g‐1 and also retains a high capacity of 541 mA h g‐1 after 250 cycles at 500 mA g‐1, which suggests that GPCS material can be a promising electrode for LIB application. A brief comparison with commercial graphite and various carbonaceous materials from literature demonstrated that the GPCS electrode was potential material for high rate LIBs.
Lithium-ion capacitors (LICs) with
the capability of high energy
and high power are considered to be attractive for advanced energy
storage applications. However, the design and fabrication of suitable
electrode materials with desirable properties by a facile approach
using cost-effective precursors are still a great challenge. In this
work, we have utilized petroleum coke, an unavoidable industrial waste
with high carbon content, as a single carbon source to synthesize
both a high surface area activated carbon cathode and a low surface
area disordered carbon anode. A lithium-ion capacitor fabricated using
all-petroleum coke-derived carbon materials exhibits a high energy
density of 80 W h/kg and a high power density of 8.4 kW/kg as well
as long life span (85% capacity retention after 10,000 charge–discharge
cycles at 1 A/g). Systematic characterization analysis demonstrates
that unique characteristics of carbon electrode materials including
hierarchical pores, high surface area, and graphene-like structured
activated carbon contribute synergistically to the outstanding performance
of the petroleum coke-based LIC. More importantly, the facile approach
adopted in the present study to synthesize both cathode and anode
materials from a single source is an effective way for high value-added
utilization of petroleum coke at the commercial level.
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