Polyol made from about 10 nm sized maghemite nanoparticles was functionalized by a hydrophilic catechol derivative, namely, dopamine. Infrared spectroscopy confirmed the grafting, whereas X-ray diffraction and transmission electron microscopy did not show either structural or microstructural change on the iron oxide particles. 57Fe Mössbauer spectrometry allowed, giving a quantitative assessment of the bonding preferences of dopamine on the iron oxide surfaces, the π-donor character of this ligand to be experimentally evidenced for the first time. These results are supplemented by ab initio modeling, expanding on previous work by considering various iron oxide surfaces and orientations. Perspectives of the work are discussed.

Combining ab initio modelling and 57 Fe Mössbauer spectrometry, we characterized the nature of the chemical linkage of aminoalkyl arenediazonium salt on the surface of iron oxide nanoparticles. We established that it is built through a metal-oxygen-carbon bonding and not a metal-carbon one, as usually suggested and commonly observed in previously studied metal or carbon-based surfaces.

We performed ab initio computations of the magnetic properties of simple iron oxide clusters and slabs. We considered an iron oxide cluster functionalized by a molecule or glued to a gold cluster of the same size. We also considered a magnetite slab coated by cobalt oxide or a mixture of iron oxide and cobalt oxide. The changes in magnetic behavior were explored using constrained magnetic calculations. A possible value for the surface anisotropy was estimated from the fit of a classical Heisenberg model on ab initio results. The value was found to be compatible with estimations obtained by other means, or inferred from experimental results. The addition of a ligand, coating, or of a metallic nanoparticle to the systems degraded the quality of the description by the Heisenberg Hamiltonian. Proposing a change in the anisotropies allowing for the proportion of each transition atom we could get a much better description of the magnetism of series of hybrid cobalt and iron oxide systems.

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Halochromic switch from the 1st to 2nd Near Infrared window of Diazapentalene-Dithienosilole copolymers is reported. The diazapentalene repeat unit presents an imine group that can be either protonated by a Bronsted acid or coordinated with a Lewis acid. As a consequence, the wavelength of maximum absorbance was switched from 840 nm to 1070 nm. Experimental data obtained by spectrophotometry and cyclic voltammetry were combined with theoretical DFT calculations to explain the reversible halochromic behavior of these copolymers and the adducts that are formed during the reactions. Since they can undergo analyte-induced absorption shifts in the near infrared, these materials should prove useful as biological/chemical sensors.

A new conjugated copolymer with alternating dithienosilole and thienoisoindigo units displays improved near-infrared absorption compared to previously reported dithienosilole-based copolymers.