We present non-adiabatic simulations of the excitation and de-excitation of an Na 12 sodium cluster irradiated by intense femtosecond lasers. Both electronic and ionic degrees of freedom are explicitly accounted for, whatever nonlinear regime is accessed. We find that the Coulomb fragmentation of the thus excited cluster depends sensitively on the laser frequency. We furthermore show that in the first 100 fs following the laser excitation, ionic degrees of freedom can safely be considered to be frozen. They then couple quickly to the electronic ones, within about another 100 fs, well before electronic excitation has fully levelled off.
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