Das Photoreduktionssystem Aceton/Isopropylalkohol wurde mit partiell deuterierten Komponenten mit Hilfe der CIDNP-Spektroskopie untersucht. Auf sehr einfache Weise konnte das CIDNP-Spektrum von Propen-2-01 erhalten werden. Die entstehenden 2-HydroxypropylRadikale bilden unkorrelierte Radikalpaare, die in die Ausgangsverbindungen disproportionieren.
A CIDNP Study of the Photoreduction System Acetone/Isopropyl AlcoholThe photoreduction system acetone/isopropyl alcohol has been studied by means of CIDNP spectroscopy. Partially deuterated components were used. The CIDNP spectrum of propen-2-01 was obtained by a simple method and it is shown, that the generated 2-hydroxypropyl radicals form uncorrelated radical pairs, which disproportionate into the starting material.
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