This work assessed Ni-based C276 alloy coatings by PTA with different degree of interaction with AISI 316L and API 5L X70 steel substrates. Track geometry, dilution and microstructure of coatings were evaluated by optical, scanning electron microscopy and X-ray diffraction. Properties were evaluated by hardness and wear tests. Microstructure exhibited austenite Ni-FCC dendrites and interdendrictic regions containing carbides. Dilution from 4,9 to 25,4% for coatings on API 5L X70 leaded to hardness ranging from 283 to 243 HV 0,5 . Otherwise, dilution between 22,3 and 41,5% for coatings on AISI 316L induced hardness from 267 to 225 HV 0,5 . Higher interaction with the substrate leaded to 19,8% increase of mass loss rate on API 5L X70 coatings. The slight difference for coatings properties deposited on different substrates indicated that the degree of interaction was the most significant factor.
Abstract:In Brazil, as in much of the academic world, there is an increasing acknowledgement among scholars that their chances of having their research noticed by a geographically diverse scientific community increase when that research is communicated in English. At the same time, much like the majority of the world, the first language of Brazil is not English, which raises one question that heretofore has not been addressed in the context of that country: How do Brazilian scholars write their research articles in English? That question drove the initial phase of the exploratory study described in the present paper, and it is one that also led the authors to discover that one key agent in the publishing process in Brazilian academia is the dissertation/thesis supervisor. Questionnaire and interview data collected from students and supervisors at a Brazilian university suggest that student and lecturer alike see the need and value of specialized writing guidance, yet neither party seems to ascribe the role of "literacy broker" (a person who contributes to the development of a text intended for publication) to the thesis supervisor in any specific way. Pedagogical implications and directions for future research are discussed.
The Laves phase reinforced CoCrMoSi alloy system has emerged as a candidate material to protect the surface of components to withstand harsh environments under wear and/or corrosion. However, previous reports have raised some concerns and restricted a wider selection of iron-based substrates to be coated, especially limiting the carbon content. This work aims to outline the Laves -Carbides phases in the microstructure and its effect on the properties of T400 alloy deposited on GGG40 ductile iron. Dilution of 26 % ensured Laves formation either as primary or secondary, due to high-silicon substrate selected. Departing from 41 % dilution, the alloy changed to a completely carbide strengthened system. Therefore, for the lowest dilution the coatings hardness is dictated by Laves phase whereas, for higher ones, carbides are the most influent phases.
A high-power diode laser was used to generate single- and multi-bead coatings of Stellite™ 6 by coaxial laser cladding over flat grey cast iron (EN-GJLP-200) as a preliminary study to develop a wear and corrosion resistant coating for brake disks on a cost-effective substrate. In this article, we have focused on a detailed quantitative analysis of the effect of different laser powers (1.5, 2.0, 2.5, 3.0, 3.5, and 4.0 kW) on the bead geometry, dilution, microstructure, and hardness. Coatings dilution or composition depends directly on the laser power as well as bead geometry. The typical microstructure of the coatings comprises a solid solution of α (hcp)- and β (fcc)-Co with a dendritic structure as a metal matrix and an interdendritic lamellar eutectic, which contains predominantly β-Co, chromium carbides Cr7C3 and Cr23C6 as well as blocky tungsten carbide W2C. Coating hardness depends on the chemical composition and microstructure that is modified by the deposition parameters. Low laser power results in high carbide fraction and most refined microstructures, accounting for harder coatings.
Environmental legislation and the electrification of vehicles place increased requirements on brake disks in terms of wear and corrosion resistance. Departing from a preliminary study, the present investigation examined the friction and wear behavior as well as the corrosion properties of Stellite™ 6 coatings on gray cast iron, which were deposited by laser cladding. The friction and wear experiments were conducted on a pin-on-disk tribometer at contact pressures of 1.0 and 2.0 MPa as well as rotation speeds of 0.2, 0.4, 0.6, 0.8, and 2.0 m/s. The pins are manufactured from an automotive semi-metallic brake pad. The friction behavior of gray cast iron and Stellite™ 6 coatings is similar under changing test conditions. The tribological behavior is strongly influenced by the microstructural and mechanical properties of the coatings and the brake pad material. A third body layer of contact patches is formed on Stellite™ 6, which mainly consists of brake pad components. The transformation of the Co-matrix (fcc → hcp), subsurface fatigue, and tribo-oxidation are the main wear mechanism for Stellite™ 6. The electrochemical characteristics were analyzed by potentiodynamic polarization, and the corrosion rate was determined with Tafel plots in 3.5% NaCl solution, respectively. Compared to gray cast iron, Stellite™ 6 coatings have a pronounced corrosion resistance due to the formation of a protective passive layer of Co and Cr oxides. This corrosion resistance is mainly influenced by the microstructure. The corrosion rate of the coatings increases in parallel with the Fe dilution.
Hardfacing is widely applied to components yet the majority of the
Resumo: Revestimentos soldados são amplamente usados para proteger componentes mecânicos entretanto a maioria das técnicas de soldagem disponíveis restringe a variedade de ligas de alta resistência que podem ser depositadas. O processo de plasma por arco transferido permite ultrapassar esta limitação ao utilizar material de adição na forma de pó, oferecendo a possibilidade de se customizar a composição dos revestimentos e em consequências as suas propriedades. A elevada resistência mecânica e inercia química das ligas de aluminetos tornam estas ligas atrativas para a proteção de componentes diversos. Entretanto a grande interação com
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