Archeological studies have found that pyrolysis liquids were already used in the time of the Neanderthal. Wood vinegar and other slow pyrolysis liquids are produced as a by-product of charcoal production. However, future business ideas may be the other way round as pyrolysis liquids may replace synthetic chemicals in the form of pesticides and biocides.Directives and regulations related to the sustainable use of pesticides govern and direct plant protection strategies towards a lower use of synthetic chemicals. It is hoped that many mega trends of global policies will boost the use of plant based products given that a reduced reliance on fossil fuel is a general target in the global food and feed production economy. Pyrolysis technology has been actively studied and developed around the world and is linked to the development of the knowledge based bio-economy. The importance and social impact of pyrolysis technologies will also be enhanced because it is a practicable technique in the sustainable use of wastes and biomasses. However, very little scientific evidence is available to support efficacy claims of wood vinegar and toxicology assessments of the products used. Wood tar has been investigated a bit more thoroughly. The aim of this review was to clarify the potential of slow pyrolysis liquids in agricultural use, in particular, in pesticide applications. In addition, some of the main challenges in developing novel bio control technologies are discussed and the barriers in the commercialization of biological control agents are revealed.
In Northern Europe, changes in climate may result in better growing conditions for many crops. However, the expected warmer and more humid conditions are favourable for Fusarium head blight infections on cereals. The Fusarium species prevalent in Nordic areas to date are the same as in Central Europe: F. avenaceum, F. culmorum, F. graminearum and F. poae. The prevalence of F. graminearum in cereal grain has already increased in Central Europe and is likely to increase in the North due to the expected changes in weather conditions, reduced tillage and the predicted increase in maize cultivation in Nordic countries. The possible weather extremes predispose cereals to Fusarium infections by increasing the populations of insect pests injuring plants. Adverse conditions may even create conditions suitable for F. subglutinans or F. verticilloides to infect maize and possibly other cereals in rotation in southern parts of Scandinavia. The importance of the species that infect in relatively dry conditions, F. langsethiae and F. poae, may also increase on winter cereals which are predicted to be more prevalent in future farming. If the number of crop species cultivated will increase and non-cereal crops are included in rotations effects of reduced tillage on Fusarium infections in grain could be limited. The predicted changes in climate towards 2050 are expected to slightly change Fusarium species composition in Northern Europe. An increase in F. graminearum and possibly the invasion of northern parts of Central Europe and Denmark by fumonisin producers is expected.
Birch distillate, a byproduct in charcoal production, has found to be a promising source for biological pesticides. The aim of this paper was to determine the yields and chemical compositions of liquid and gaseous products from the slow pyrolysis of birch hardwood, which is needed in the commercialization process of the byproduct. Test runs were performed using three different retorts. Distillates, aqueous phases, settled tars, wood vinegars, and gases were analyzed with an analytical scheme developed. About 95 wt % of the aqueous phases was analyzed. The main compounds were water, acetic acid, methanol, hydroxypropanone, furfurals, acetone, and syringol, catechol, and phenol derivatives, and sugarlike compounds. The tar and polycyclic aromatic hydrocarbons contents of aqueous phases were low, or they could be lowered by simple water addition when needed. On the basis of compositions, birch wood vinegars have potential to be used for example as biodegradable pesticides, to replace synthetic pesticides. At low temperatures, formed tar-free distillates (predistillates) can be separated from the main distillate and utilized. Because of their low pH and high organic load, they cannot be disposed to the environment without treatment. The amount of polycyclic aromatic hydrocarbons in the tars has to be considered, and therefore, the tars were suggested to be utilized mainly as energy. The gases are promising to be utilized, in addition to the process itself, for other energy needs. The differences obtained for the products of different processes were mainly between batch and continuous processes. The detailed compositions of the products may be exploited by enterprises and authorities for registration purposes in the commercialization process.
Strawberry leaves contain high amounts of diverse phenolic compounds potentially possessing defensive activities against microbial pathogens and beneficial properties for human health. In this work, young strawberry plants were treated with two plant activators, S-methylbenzo-1,2,3-thaidiazole-7-carbothiate (BTH) and birch wood distillate. Phenolic compounds from activator-treated and control leaves were subjected to quantitative analyses by HPLC-DAD, HPLC-ESI-MS, and microQTOF ESI-MS. Thirty-two different phenolic compounds were detected and characterized, and 21 different ellagitannins constituted the largest group of compounds in the strawberry leaves (37.88-45.82 mg/g dry weight, 47.0-54.3% of total phenolics). Treatment with BTH resulted in higher levels of individual ellagitannins, whereas treatment with birch wood distillate strongly increased the levels of chlorogenic acid in strawberry leaves compared with the control. The results suggest that different plant activators may be useful tools for the activation of different branches in the phenylpropanoid biosynthesis in strawberry.
In an experimental set‐up in and around Helsinki, Finland (60°N, 25°E), we have detected pest insect immigration using weather radars and insect traps in the field. This study was part of a project to develop a system to give warning of a possible arrival of long‐range migrant insect pests. Bird‐cherry aphid, Rhopalosiphum padi, and diamondback moth, Plutella xylostella, were found on the ground following migrations in warm airstreams at the end of May 2007. This migration episode was successfully forecast by the meteorologists in the project team. For the summer 2008, we developed a pest insect immigration alarm system based on SILAM, a Finnish Meteorological Institute atmospheric dispersion model. The first important pest insect immigration occurred in late June, bringing bird‐cherry aphids. Our alarm system correctly produced a warning of this immigration. We studied the migration path in the observed events in 2007 and 2008 with the help of the atmospheric dispersion model. Weather radars frequently showed rain echo over the area, but there was also a lot of echoes originating from the migrating insects. Using the polarimetric weather radar in Helsinki, we could differentiate insects from other sources of echoes. Insects were common in layers below 1 km, and were observed up to height of about 2.5 km. Using Doppler weather radars we were able to observe the speed and direction of the migration. The experiment showed that an atmospheric dispersion model is an effective tool for predicting the movement of airborne migrants. The alarm system would work still better, if the sources of the immigrants were known in more detail. In addition, the very simple modelling of airborne migration should be refined. Weather radars, and especially polarimetric systems, are able to detect insect migrations and reveal details of the phenomenon not obtainable by other means.
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