Nanostructured PdO materials with promising catalytic properties were successfully synthesized by the controlled thermal decomposition in air of three Pd(II) complexes containing Pd(II) ion, ofloxacin drug and amino acid. The Pd(II) complexes which were used as precursors were [Pd(OFL)(Gly)]Cl, [Pd(OFL)(Ala)]Cl, and [Pd(OFL)2]Cl2, where Gly is glycine amino acid, Ala is alanine amino acid, and OFL is ofloxacin. Structural and morphological properties of the synthesized PdO materials were obtained using FTIR, XRD, SEM, and EDX techniques. The XRD results confirm the tetragonal structure of PdO. The obtained PdO materials were tested as a catalyst for the heterogeneous degradation of H2O2 solution. The results revealed that PdO could effectively degrade H2O2.
KEY WORDS: PdO, Nanoparticles, Photocatalytic efficiency, Wastewater treatment
Bull. Chem. Soc. Ethiop. 2021, 35(1), 107-118.
DOI: https://dx.doi.org/10.4314/bcse.v35i1.9
The aim of the present work is to follow the capacity of adsorption of CO2 by natural cellulose nanofibers, extracted from banana peel and mixed with nano-silver. Following initial characterization, the raw material and the isolated sample were investigated by Energy Dispersive Analysis (EDS), X-ray diffraction (XRD); Fourier- Transformed infrared spectroscopy (FT-IR) and thermal analysis (Hi Res TG). Nitrogen gas adsorption-desorption isotherms of isolated cellulose nanofibers reveal a type I- isotherm, specific to the nano-porous materials.The results of adsorption isotherms of CO2 at 304 K showed that the extracted sample exhibit an adsorption capacity of 12 mmol/g of CO2.
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