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A simulated one-step process has been developed for the production of foam core particleboards using rigid polyurethane as the core layer. The results showed that the different techniques used for surface layer separation (unresinated particles and sprayed water) and foam injections (open system and closed system) had no influences on panels' characteristics. Mechanical properties (e.g., bending strength and internal bond strength) were mostly influenced by the surface layer thickness, while the water absorption and edge screw withdrawal were influenced by the foam cell structure. The use of sprayed water for surface layer separation doubled the formaldehyde emission (FE) of the panels. The addition of urea (based on 10% of the dry resin) to the sprayed water had a positive effect of reducing the final FE. Furthermore, increasing the surface layer thickness had a positive, linear relationship with FE.

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One‐step manufacturing process (in‐situ foaming) provide great potential for the production of foam core panels. Polyurethane (PU) foam showed good applicability for use for in‐situ foaming. Here, the effect of ingredient ratios of rigid PU foam on foam performance and panel properties is investigated. It was observed that the isocyanate (ISO) content and polyols (PO) type and content significantly change the foam and panel properties. Foam cell density, as the most important factor influencing the foam characteristics, was higher in foams with higher ISO and polyether content. Bending strength, internal bond and screw withdrawal resistance of the foam core panels were significantly enhanced when the ISO and polyether content was increased in the foam formulation. Varying the ISO content had no influence on panel properties with higher content of polyester (60%) in the PO blend. Varying the foam ingredient ratios did not change the thickness swelling, while the water absorption was dependent on the foam components ratios. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 44722.

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This study investigated the interaction between particle size and mixing ratio on the porosity of particleboard and in consequence its effect on the physical and mechanical properties of panels. Tea Oil Camellia Shell (TOCS), which could provide 1.8 million tons of lignocellulose raw material annually, can be a useful resource for particleboard production. In that regard, particleboards with different particle sizes (coarse and fine) and mixing ratios (wood and TOCS) bonded with Polymethylene polyphenyl polyisocyanate (pMDI) were investigated. The results showed that particleboard made with TOCS particles had higher densities than those of commercial wood particles. Furthermore, particleboards made with fine particles had lower porosity. The average values for physical and mechanical properties have shown that except for thickness swelling (TS), most properties were better with coarse particles. In terms of all properties, results showed that adding 50% of commercial wood in conjunction with TOCS particles regardless of particle size can offer acceptable results, which qualified all requirements of EN 312:2010 standard for P2-type particleboard (boards for interior fitments (including furniture) for use in dry conditions). In addition, due to the porous structure of the shells, TOCS-based particleboards have better thermal conductivity compared to wood-based particleboards.

The use of agricultural biomass composites as new construction and building materials has grown rapidly in recent decades. Considering that energy consumption is one of the most important factors in production, the aim of this work is to examine how heat transfer is affected at various ratios and combinations of three-layer tea oil camellia shell (TOCS) based particleboard with the purpose of creating a mat-forming structure, which has the best physical and mechanical properties for furniture and construction use in a dry environment and consumes the least amount of energy. Additionally, it investigated how raw materials type affects the curing process of polymeric methylene diisocyanate (pMDI) using differential scanning calorimetry (DSC). According to the obtained data, the centerline temperature could reach a maximum of 125 °C after 3 min regardless of the materials or combinations, while the pMDI curing time was 100–110 °C. The results demonstrated that efficient heat transfer could help resin polymerization and improve panel properties. The effect of raw materials on the curing behavior of resin indicated that TOCS particles somehow caused more heat reactions at the curing point. It appeared that particleboard with a ratio of 40% commercial wood particles in the surface layers and 50% TOCS particles (mesh size: −3 + 14) in the core layer with a modulus of rupture (MOR) of 11.29 N/mm2 and internal bonding (IB) of 0.78 N/mm2 has the best properties and met EN 312: 2010 standard requirements for particleboard P2.