Levels of 10 heavy metals in cattle egret chick feathers, prey, and surrounding soils from three heronries in Punjab Province, Pakistan, were assessed by atomic absorption spectrophotometry. Mean levels of cadmium (Cd), iron (Fe), chromium (Cr), and lithium (Li) in feathers, manganese (Mn), cobalt (Co), and nickel (Ni) in prey, and lead (Pb), iron (Fe), chromium (Cr), zinc (Zn), cobalt (Co), and lithium (Li) in soils were significantly different among Trimun Headworks, Shorkot, and Mailsi heroneries. Mean levels of Pb (43.10 μg/g), Cr (35.77 μg/g), Co (18.34 μg/g), Cu (0.20 μg/g), and Ni (0.22 μg/g) in feathers were significantly greater at Mailsi, and Mn (3.07 μg/g), Zn (18.83 μg/g), and Li (1.5 μg/g) levels were significantly greater at Shorkot. Multivariate analysis identified that some metals, such as Fe, Zn, and Li, in feathers were either associated with natural sources or with human-related activities, whereas Ni, Cr, Pb, Cd, Cu, Co, and Mn were correlated mainly with anthropogenic processes. Alarming levels were recorded for Cr, Pb, and Cd in feathers that were above threshold levels that may affect cattle egret flighting capacity and reproduction, thus leading to their population decline in Punjab Province. The results of this study provide evidence for the potential of feathers of cattle egret to be used as a biomonitor for the local heavy-metal contamination.

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Automatic generation control (AGC) is primarily responsible for ensuring the smooth and efficient operation of an electric power system. The main goal of AGC is to keep the operating frequency under prescribed limits and maintain the interchange power at the intended level. Therefore, an AGC system must be supplemented with modern and intelligent control techniques to provide adequate power supply. This paper provides a comprehensive overview of various AGC models in diverse configurations of the power system. Initially, the history of power system AGC models is explored and the basic operation of AGC in a multi-area interconnected power system is presented. An in-depth analysis of various control methods used to mitigate the AGC issues is provided. Application of fast-acting energy storage devices, high voltage direct current (HVDC) interconnections, and flexible AC transmission systems (FACTS) devices in the AGC systems are investigated. Furthermore, AGC systems employed in different renewable energy generation systems are overviewed and are summarized in tabulated form. AGC techniques in different configurations of microgrid and smart grid are also presented in detail. A thorough overview of various AGC issues in a deregulated power system is provided by considering the different contract scenarios. Moreover, AGC systems with an additional objective of economic dispatch is investigated and an overview of worldwide AGC practices is provided. Finally, the paper concludes with an emphasis on the prospective study in the field of AGC.

Long-term transformer oil usage deteriorates the thermal and dielectric properties of the oil. The main aim of our work is to find a suitable replacement for mineral oil with superior characteristics. Titanium Oxide (TiO 2), Zinc Oxide (ZnO), and Aluminum Oxide (Al 2 O 3) Nano Particles (NPs) are used inside the virgin mineral oil to form Nano Fluids (NFs). NFs are subjected to accelerated multi-aging (thermal and electrical) for 1000 hours. The special aging chamber is designed to apply electrical and thermal stresses to the oil under consideration. Thermal and dielectric characteristics of the NFs are determined using breakdown voltage, water content, tan delta, flash point, viscosity, and pour point tests. The aforementioned tests are conducted before and after the accelerated aging of the samples. Thermal and dielectric characteristics of ZnO based NFs are found superior to other NPs. ZnO NPs show the highest breakdown voltage and minimum values of water content, tan delta, pour point, and viscosity. The highest value of flash point confirmed the superiority of ZnO NF over other NFs even after accelerated multi-aging. Therefore, the experimental analysis concluded that ZnO based NFs possess remarkably good thermal and dielectric properties as a replacement of mineral oil in the transformer operation. INDEX TERMS Mineral oil, multi-aging, ZnO, aluminium oxide, titanium oxide, nickel oxide, dissipation factor.

Two new cationic surfactants, n-hexadecyl-3-methylpyridinium bromide and n-heptadecyl-3-methylpyridinium bromide have been synthesized and characterized in solid state by FT-IR, and in solution by 1 H- and 13 C-NMR spectroscopy. The values of critical micelle concentration (CMC) were determined by UV-visible spectroscopy and conductometry. Interaction of synthesized surfactants with two anionic drugs, i.e., diclofenac sodium {[2-(2, 6-Dichloroanilino) phenyl] acetic acid} and ketoprofen [(RS)-2-(3-benzoylphenyl) propionic acid] was studied by UV-visible spectroscopy. Binding constant (K), Gibb's free energy (ΔG) and number of drug molecules (n) per micelle were also calculated. These synthesized surfactants were proved to be efficient in increasing the solubility and bioavailability of drug molecules. In order to check the carrier efficiency of synthesized surfactants against bioactive coordinate, on complexes, interaction of recently reported bioactive zinc complexes was tested with synthesized cationic surfactants by conductometric measurements. Mole fractions (X cmc ) and Gibbs free energy (ΔG cmc ) values were also calculated. Both surfactants were further screened for anti-fungal and anti-bacterial activities.