Bionic condensate microdrop self‐propelling (CMDSP) surfaces are attracting intensive interest due to their academic and commercial values. Up to now, it is still a great challenge to design and fabricate CMDSP nanostructures with superior condensation heat transfer (CHT) efficiency. Here, it is reported that the CHT coefficient of copper surfaces can be enhanced maximally ≈320% via in situ growth and geometric regulation of closely packed aligned nanoneedles with CMDSP function. These experiments and theoretical analyses indicate that reducing the interspaces of nanoneedles can help reduce the departure diameters of condensate microdrops and increase their nucleation density, both of which are beneficial to enhance CHT. In contrast, increasing the tip size and height of nanoneedles can increase drop departure diameters and film‐layer thermal resistance, respectively, either of which is disadvantageous to enhance CHT. Clearly, only considering superhydrophobic effect is insufficient and both choosing ideal nanoarchitectures and optimizing their geometric parameters are very crucial to realize high‐efficiency CHT, which optimization can be achieved via simply controlling growth time of nanostructures. These findings offer new insights into the design and development of first‐rank CHT interface nanomaterials.
Vulnerable atherosclerotic (AS) plaque is the major cause of cardiovascular death. However, clinical methods cannot directly identify the vulnerable AS plaque at molecule level. Herein, osteopontin antibody (OPN Ab) and NIR fluorescence molecules of ICG co‐assembled Ti3C2 nanosheets are reported as an advanced nanoprobe (OPN Ab/Ti3C2/ICG) with enhanced photoacoustic (PA) performance for direct and non‐invasive in vivo visual imaging of vulnerable AS plaque. The designed OPN Ab/Ti3C2/ICG nanoprobes successfully realize obvious NIR fluorescence imaging toward foam cells as well as the vulnerable AS plaque slices. After intravenous injection of OPN Ab/Ti3C2/ICG nanoprobes into AS model mice, in vivo imaging results show a significantly enhanced PA signal in the aortic arch accumulated with vulnerable plaque, well indicating the remarkable feasibility of OPN Ab/Ti3C2/ICG nanoprobes to distinguish the vulnerable AS plaque. The proposed OPN Ab/Ti3C2/ICG nanoprobes not only overcome the clinical difficulty to differentiate vulnerable plaque, but also achieve the non‐invasively specific in vivo imaging of vulnerable AS plaque at molecule level, greatly promoting the innovation of cardiovascular diagnosis technology.
A new fused‐ring electron acceptor FOIC1 is designed and synthesized. FOIC1 exhibits intense absorption in the range of 600–1000 nm, the highest occupied molecular orbital (HOMO)/the lowest unoccupied molecular orbital (LUMO) energy levels of −5.39/−3.99 eV, and electron mobility of 1.8 × 10−3 cm2 V−1 s−1. Organic solar cells based on sequentially processed heterojunction (SHJ) with an unusual inverted structure are fabricated. Through sequentially spin‐coating polymer donor PTB7‐Th as the bottom layer and acceptor FOIC1 as the top layer, a better vertical phase distribution is formed in this SHJ compared with that in traditional bulk heterojunction (BHJ). In the upper‐half part, a more balanced donor/acceptor distribution is beneficial for exciton dissociation. At the bottom interface, more FOIC1 accumulation is beneficial for exciton generation and charge transport. Overall, the SHJ cells exhibit power conversion efficiency as high as 12.0%, higher than that of the BHJ counterpart (11.0%).
Ternary blends have been considered as an effective approach to improve power conversion efficiency (PCE) of organic solar cells (OSCs). Among them, the fullerene-containing ternary OSCs have been studied extensively, and their PCEs are as high as over 14%. However, all non-fullerene acceptor ternary OSCs are still limited by their relatively lower PCEs. In this work, we used wide-bandgap benzodithiophene-difluorobenzotriazole copolymer FTAZ as the donor, low-bandgap fused-ring electron acceptor (FREA), fused tris(thienothiophene) end-capped by fluorinated 1,1-dicyanomethylene-3-indanone (FOIC) as acceptor, and two medium-bandgap FREAs, indaceno-dithiophene endcapped by 1,1-dicyanomethylene-3-indanone (IDT-IC) and indacenodithiophene end-capped by 1,1-dicyanomethylene-3-benzoindanone (IDT-NC), as the third components to fabricate the ternary blends FTAZ:FOIC:IDT-IC and FTAZ:FOIC:IDT-NC, and investigated the effects of the third components on the performance of ternary OSCs. Both IDT-IC and IDT-NC are based on the same indacenodithiophene core but contain different terminal groups (phenyl and naphthyl). Relative to IDT-IC with phenyl terminal groups, IDT-NC with naphthyl terminal groups has extended π-conjugation, down-shifted lowest unoccupied molecular orbital (LUMO), red-shifted absorption and higher electron mobility. The binary devices based on the FTAZ:FOIC, FTAZ:IDT-IC and FTAZ:IDT-NC blends exhibit PCEs of 9.73%, 7.48% and 7.68%, respectively. Compared with corresponding binary devices, both ternary devices based on FTAZ:FOIC:IDT-IC and FTAZ:FOIC:IDT-NC exhibit better photovoltaic performances. When the IDT-IC weight ratio in acceptors is 50%, the FTAZ:FOIC:IDT-IC ternary devices exhibit the best PCE of 11.2%. The ternary-blend OSCs yield simultaneously improved open-circuit voltage (VOC), short-circuit current density (JSC) and fill factor (FF) compared with the binary devices based on FTAZ:FOIC. The higher VOC is attributed to the higher LUMO energy level of IDT-IC compared with FOIC. The improved JSC is attributed to the complementary absorption of FOIC and IDT-IC. The introduction of IDT-IC improves blend morphology and charge transport, leading to higher FF. The FTAZ:FOIC:IDT-NC system yields a higher PCE of 10.4% relative to the binary devices based on FTAZ:FOIC as the active layer. However, the PCE of the FTAZ:FOIC:IDT-NC-based ternary devices is lower than that of the FTAZ:FOIC:IDT-IC-based ternary devices. Compared with the binary devices based on FTAZ:FOIC, in FTAZ:FOIC:IDT-NC-based ternary devices, as the ratio of the third component increases, the VOC increases due to the higher LUMO energy level of IDT-NC, the FF increases due to optimized morphology and improved charge transport, while the JSC decreases due to the overlapped absorption of FOIC and IDT-NC. The terminal groups in the third components affect the performance of the ternary OSCs. The lower LUMO.
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