0-3 composite ranging between 0 and 3, of ferroelectric ceramic lead zirconate titanate (PZT) and thermoplastic elastomer polyurethane (PU) were fabricated. The pyroelectric and dielectric properties of the hot-pressed thin film samples of various PZT volume fractions were measured. The experimental dielectric permittivities and losses agreed reasonably well with the Bruggeman model. The room temperature pyroelectric coefficients of the composites were found to increase linearly with PZT volume fraction and substantially larger than expected. For example, for a composite with 30% PZT, its pyroelectric coefficient is about 90 C/m 2 K at room temperature, which is more than tenfold of a PZT/PVDF composite of the same ceramic volume fraction. We propose a model in which the electrical conductivity of the composite system is taken into consideration to explain the linear relationship and the extraordinarily large pyroelectric coefficients obtained.
Electrostriction of a ferroelectric inclusion/nonferroelectric matrix composite system was studied. The samples were prepared by blending the lead zirconate titanate ͑PZT͒ particles with the thermoplastic polyurethane through extrusion and subsequently by hot pressing. Quasistatic cyclic electric fields were applied across the samples while strains and currents were monitored simultaneously. It was found that the electrostriction of the composites depended on the applied electric field in a hysteretic manner. In particular at the high-field regime, the samples exhibited a reversal in the electrostrictive strain. This switching effect occurred at a critical field which was inversely proportional to the PZT content. An associated increase in the displacement current with the critical field was also observed. It indicates that the switching in strain of the composites was mainly due to the flipping of the PZT dipoles in the nonferroelectric polymer matrix. A model was developed for describing the electrostriction behavior of this composite system and the calculated results are comparable to the experimental curves. The success of this theoretical model encourages its application further to the ferroelectric-ferroelectric composite systems.
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