In this work, nylon 6 core–chitosan/poly(vinyl alcohol) (PVA) shell hydrogel nanofibers (NCNFs) were fabricated by coaxial solution blowing for BSA adsorbing.
This study aims to develop novel hybrid composite membranes (NHMs) by impregnating Nafion solution into the porous sulfonated poly(ether ether ketone)/polyhedral oligomeric silsesquioxanes (SPEEK/POSS) nanofibers (NFs). The composite membrane was prepared by solution blowing of a mixture of SPEEK/POSS solution. The characteristics of the SPEEK/POSS NFs and the NHMs, including morphology, thermal stability, and performance of membrane as PEMs, were investigated. The performance of NHMs was compared with that of Nafion117 and SPEEK/Nafion composite membranes. Results showed that the introduction of POSS improved the proton conductivity, water swelling, and methanol permeability of membranes. A maximum proton conductivity of 0.163 S cm 21 was obtained when the POSS content was 6 wt % at 808C, which was higher than that of Nafion117 and SPEEK/Nafion. NHMs could be used as proton exchange membranes (PEMs) for fuel cell applications.
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