Polyhedral liquid marbles/plasticines are prepared using (sub)millimeter‐sized polymer plates as a stabilizer and water as an inner liquid. Precise control of size and shape can be successfully performed by tuning the size ratio of the water droplet and the plate, number of plates adsorbed to the droplet, coalescence (jointing) of multiple polyhedral liquid marbles/plasticines, and application of external mechanical stress. Thanks to interfacial jamming of the plates, plastic deformation of the liquid marbles/plasticines is achieved. The authors are able to fabricate liquid marbles/plasticines with various shapes including A–Z letters of alphabet. Liquid marble/plasticine with an aspect ratio exceeding 800, the largest aspect ratio ever reported, is also successfully prepared; the length of the liquid marble/plasticine exceeded 1.5 m. The liquid marbles can be picked up and be piled up on top of each other using tweezers or fingers. Furthermore, Janus‐type liquid marbles/plasticines with different curvatures and different stabilizers in a single liquid marble/plasticine can be fabricated by coalescence (jointing) of near‐spherical and cuboid liquid marbles/plasticines stabilized by plates with different sizes. An internal liquid flow from the near‐spherical liquid marble to the cuboid liquid marble/plasticine immediately after jointing is observed, making this system act as a micropump.
The structural diversity found in terpene metabolism is mostly elaborated by olefmic cyclizations of five basic acyclic precursors.1 The biological strategy for construction of new C-C bonds involves intramolecular electrophilic alkylation of remote double bonds to a cationic center generated by the ionization of allylic pyrophosphates,2 in which the enzyme may require a divalent cation, Mg2+ or Mn2+, for catalytic activity.3 Formation of limonene from neryl precursors is commonly assumed to be a suitable model
Liquid marbles were prepared using a water droplet and nonprotonated hydrophobic poly(2-N,Ndiisopropylaminoethyl methacrylate) (PDiPAEMA) powder. Although the nonprotonated PDiPAEMA was hydrophobic, PDiPAEMA became hydrophilic because of the protonation of the pendant tertiary amino groups under acidic conditions. Therefore, liquid marbles stabilized with PDiPAEMA powder could float on a neutral to basic water surface, but they immediately disintegrated on an acidic water surface. Furthermore, the liquid marbles floating on the water surface disintegrated in response to CO 2 gas because the water became acidic as a result of carbonic acid formation.
Conductive polymer coatings were successfully adsorbed to hexagonal polyethylene terepthalate plate surfaces after silane coupling and sulfonation were performed to promote intermolecular adhesion. Conducting particle coatings were verified via scanning...
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.