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A facile and effective approach for the improvement of localized surface plasmon resonance (LSPR) biosensors based on silver-core and gold-shell nanoparticles (Ag@AuNPs) on a glass substrate was investigated. Silver nanoparticles (core) with thin gold shells on a transparent indium tin oxide (ITO) coated glass surface were prepared by sequential electrodeposition, and the influence of the thickness of the gold shell was systematically investigated. The experimental results indicate that the properties of an LSPR band of ultrathin (∼1.3 nm) gold-shell coated silver nanoparticles are very similar to those of silver nanoparticles alone. The refractive index (RI) sensitivities of the metal nanostructures are calculated as 123 and 220 nm/RIU for the silver cores (∼480 nm of LSPR peak) and Ag@AuNPs (∼503 nm of LSPR peak), respectively, on the ITO substrate. The RI sensitivity of Ag@AuNPs was significantly enhanced by coating the silver nanoparticles with an ultrathin gold shell. This core-shell platform was also applied to the fabrication of biosensors. Thus, this strategy can be used to construct inexpensive, stable, versatile, and sensitive LSPR biosensors.

A plasmonic probe based on gold nanoparticles (AuNPs) on a solid substrate for the detection of Pb2+ was developed.

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In this paper, the sensitization on electrochemiluminescent (ECL) reaction of luminol from reactive oxygen species (ROSs) in neutral medium was studied. The powerful sensitization from ROSs even related with organics and organisms were examined under selected conditions which were suitable for biochemical analysis. The results indicated that whether the enhancers were dissolved in solutions or immobilized on the surface of conventional electrodes, stronger ECL intensity of luminol could be obtained. Enhanced ECL helped to provide groundwork for the detection of biomolecules for which would further enhance or quench the ECL signals. The technique may provide new means in a variety of fields such as clinical diagnostics, immunological analysis and environmental monitoring due to its simplicity and high efficiency.

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