Electroplated Ni/Au over Cu is a popular metallization for PCB finish as well as for component leads, especially wirebondable high frequency packages, where the gold thickness requirement for wirebonding is high. The general understanding is that less than 3 wt% of Au is acceptable in SnPb solder joints. However, little is known about the effect of Au content on the reliability of SnAgCu solder joints. The purpose of this study is to determine the acceptable level of Au in SAC305 solder joints. Three different package platforms with different Au thicknesses were assembled on boards with two different Au thicknesses using a standard surface mount assembly line in a realistic production environment. The assembled boards were divided into three groups: as-built, isothermally aged at 125°C for 30 days, and isothermally aged at 125°C for 56 days. All boards were then subjected to accelerated mechanical reliability tests including random vibration and drop testing. The results show that solder joints with over 10 wt% Au are unacceptable. If Cu is available to dissolve in the solder joint, then an Au content under 5 wt% will not significantly degrade the reliability of the solder joint. When Ni layers are present on both the board and component sides of the interface, this limits the ability of Cu to dissolve into the solder joint and hence an Au content under 3 wt% is acceptable. The failure mechanism for solder joints with high Au content is fractures through the AuSn 4 IMC. Our comprehensive long-term reliability study did not confirm the finding by Ho et al. (2002) that the weak interface between (Au, Ni)Sn 4 and Ni 3 Sn 4 results in brittle interfacial failure. Additional findings confirmed the danger of placing parts near high stress areas and that a high level of voiding reduced reliability.
One of the challenges in an experimental study of solder joint reliability is to determine when cracks occur in a solder joint or when a solder joint fails. Cracks in a real solder joint are difficult to identify using an X-Ray system. Cross-sectioning and scanning electron microscopy (SEM) is a destructive method. A common non-destructive test method is to monitor resistance increase in a solder joint or a daisy-chain. However, no scientific research has been done in establishing the relationship between the crack area of an interconnection and the change in resistance of the interconnection. This paper proposes a method of defining failure criteria as the resistance increase in a solder joint exceeding a threshold. The threshold is determined by k times the range over the natural variation in resistance measured by a measurement system. The natural variation by random cause is judged using X-bar and R charts. The principles of defining failure criteria are to be able to detect failure of solder joints as early as possible with minimum false detection due of measurement system error/variation. An experimental study confirmed that a full crack of an interconnection occurs when the increase of resistance in the interconnection is 10 times the natural variation of resistance change. The results of this study could be used to narrow the definition of failure in consensus standards IPC 9701A, JESD22-B111, and IPC/JEDEC-9702.
Au over Ni on Cu is a widely used printed circuit board (PCB) surface finish, under bump metallization (UBM), and component lead metallization. It is generally accepted that less than 3 wt.% Au in Sn-Pb solder joints inhibits formation of detrimental intermetallic compounds (IMC). However, the critical limit for Au content in Pb-free solder joints is not well established. Three surface-mount package platforms, one with a matte Sn surface finish and the others with Ni/Au finish, were soldered to Ni/Au-finished PCB using Sn-3.0Ag-0.5Cu (SAC305) solder, in a realistic manufacturing setting. The assembled boards were divided into three groups: one without any thermal treatment, one subjected to isothermal aging at 125°C for 30 days, and the third group aged at 125°C for 56 days. Representative solder joints were cross-sectioned and analyzed using scanning electron microscopy (SEM) and energy-dispersive x-ray spectroscopy (EDX) to investigate the evolution of the solder joint morphology as a function of Au content and isothermal aging. It was found that, if Cu is available to dissolve in the solder joint, the migration of AuSn 4 from the bulk to the interface as a result of thermal aging is mitigated.
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