Juan Granifo scite author profile

Complexes containing phosphorus-donor ligands, [Mo(CO),(PPh,)(pa)] (pa = pyridine-2-carbaldehyde azine), bis(diphenylphosphino)ethane], have been characterised by infrared and electronic spectroscopy, cyclic voltammetry and for the [M02(Co),(p-dppe)(p-p)] complex a single crystal X-ray structure. All of the complexes show strong solvatochromism which has been analysed both by using the empirical parameter E*MLCT and by using McRae's equation. The results are compared with those of their parent complexes [Mo(CO),(pa)] and [Mo,(CO),(p-pa)], and with the results of extended-Hiickel calculations with charge iteration. [Mo2(Co),(PPh3>2(pL-pa)l 9 [Mo2(Co)7(PPh3>(p-pa)l and [Mo2(Co>6(pL-dppe)(C-Pa)l Cdppe = ,2-

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Juan Granifo

Mononuclear and binuclear rhenium(I) carbonyl complexes of 2,4,6-tris(2-pyridyl)-1,3,5-triazine (TPT), [{ReCl(CO)3}n(TPT)] (n=1, 2), and the formation of mixed-metal compounds with Re–TPT–M (M=MnII, CoII, CuII) bonds

Hydrogen bonding and π-stacking interactions in the zipper-like supramolecular structure of the monomeric cadmium(II) complex [Cd(pyterpy)(H2O)(NO3)2] (pyterpy=4′-(4-pyridyl)-2,2′:6′,2′′-terpyridine)

A novel hybrid terpyridine–pyrimidine ligand and the supramolecular structures of two of its complexes with Zn(II) and acetylacetonato: The underlying role of non-covalent π⋯π contacts and C–H⋯X(O, N, π) hydrogen bonds

The novel ligand 4′-phenyl-3,2′:6′,3′′-terpyridine (L) and the supramolecular structure of the dinuclear complex [Zn2(μ-L)(acac)4]·H2O (acac=acetylacetonato)

Structural and coordinating properties of platinum(II) chloride complexes with polypyridyl ligands. Single crystal X-ray structure of [Pt(ddpq)Cl2]·H2O (ddpq=6,7-dimethyl-2,3-di(2-pyridyl)quinoxaline)

Synthesis and dynamic NMR studies of stereochemical non-rigidity in rhenium(I) complexes of 2,6-bis[1-(phenylimino)ethyl]pyridine derivatives

Coordination mode of some polypyridyl ligands towards the platinum(II) complexes [Pt(dppf)(H2O)2](CF3SO3)2 (dppf=1,1′-bis(diphenylphosphino)ferrocene) and [Pt(Me2SO)2Cl2]. Crystal structure of the seven-membered chelate ring complex [Pt(dpq)Cl2] (dpq=2,3-di(2-pyridyl)quinoxaline)

Mono- and di-nuclear complexes of molybdenum carbonyl derivatives with pyridine-2-carbaldehyde azine and phosphines: syntheses, structure, spectroscopic and electrochemical characterisation and solvatochromic effects

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