Hydrogen bonding and π-stacking interactions in the zipper-like supramolecular structure of the monomeric cadmium(II) complex [Cd(pyterpy)(H2O)(NO3)2] (pyterpy=4′-(4-pyridyl)-2,2′:6′,2′′-terpyridine)

Self‐Assembly, Disassembly, and Reassembly of Gold Nanorods Mediated by Bis(terpyridine)–Metal Connectivity

“…Moreover, the mono-terpyridine-CdA C H T U N G T R E N N U N G (H 2 O)A C H T U N G T R E N N U N G (NO 3 ) 2 adduct has been reported in the presence of excess CdA C H T U N G T R E N N U N G (NO 3 ) 2 ·4 H 2 O. [21] Reassembly of the hybrid with added additional Cd II was not feasible; however, since Cd II -based complexes are demonstrably more labile than the corresponding Fe II -based complexes, the (Au NR)-(SS-monotpy-Cd II ) n hybrids (Scheme 3 B) were obtained by disassembling the < (Au NR)-…”

A novel infinite 1D covalent chain of end-to-end thiocyanato bridged heptacoordinated cadmium(II)Schiff base: π…π interaction and weak C–H…S hydrogen bonded supramolecule

“…1. The coordination polyhedron [15] around each cadmium is best described as distorted pentagonal bipyramid with CdN 6 S chromophore. The distortion from ideal pentagonal bipyramid geometry is due to the asymmetric nature of the bound tetradentate Schiff base and the deviation of the refine angles formed at each metal centre.…”

Unusual perchlorate binding in heptacoordinated cadmium(II)thiocyanate containing a pentadentate Schiff base

“…This rare binding mode (Cd-O1) of the counter anion facilitates a heptacoordination around cadmium. The degrees of distortion from an ideal pentagonal bipyramidal geometry are reflected in the equatorial (67.13 (16) (5)) Å , comparable to the corresponding values in similar systems [11][12][13][14]. The Cd-O1 (2.692(5) Å ) distance is much larger compared to the Cd-N distances.…”

“…Schiff bases have recently [9a,10] been focused by the coordination chemists as versatile organic blockers because of their preparative accessibilities, structural varieties and varied denticities. Pseudohalide like thiocyanate [11] is a putative ambidentate ligand and cadmium is well-suited [12][13][14] to this study as its d 10 configuration permits a wide range of symmetries and coordination numbers. Report of six-coordinated Cd(II) complex [15] with perchlorate bindings by Jan Fábry et al has prompted us to develop new luminous materials with superstructures via different non-covalent forces.…”