Activation of dinitrogen plays an important role in daily anthropogenic life, and the processes by which this fixation occurs have been a longstanding and significant research focus within the community. One of the major fields of dinitrogen activation research is the use of multimetallic compounds to reduce and/or activate N2 into a more useful nitrogen-atom source, such as ammonia. Here we report a comprehensive review of multimetallic-dinitrogen complexes and their utility toward N2 activation, beginning with the d-block metals from Group 4 to Group 11, then extending to Group 13 (which is exclusively populated by B complexes), and finally the rare-earth and actinide species. The review considers all polynuclear metal aggregates containing two or more metal centers in which dinitrogen is coordinated or activated (i.e., partial or complete cleavage of the N2 triple bond in the observed product). Our survey includes complexes in which mononuclear N2 complexes are used as building blocks to generate homo- or heteromultimetallic dinitrogen species, which allow one to evaluate the potential of heterometallic species for dinitrogen activation. We highlight some of the common trends throughout the periodic table, such as the differences between coordination modes as it relates to N2 activation and potential functionalization and the effect of polarizing the bridging N2 ligand by employing different metal ions of differing Lewis acidities. By providing this comprehensive treatment of polynuclear metal dinitrogen species, this Review aims to outline the past and provide potential future directions for continued research in this area.

Lithium–sulfur batteries are one of the most promising next-generation high-density energy storage systems. Despite progress, the poor electrical conductivity and cycling stability of sulfur cathodes still hinder their practical implementation. Here, we developed a facile approach for the engineering of Janus double-sided conductive/insulating microporous ion-sieving membranes that significantly enhance recharge efficiency and long-term stability of Li–S batteries. Our membrane consists of an insulating Li-anode side and an electrically conductive S-cathode side. The insulating side consists of a standard polypropylene separator, while the conductive side is made of closely packed multilayers of high-aspect-ratio MOF/graphene nanosheets having a thickness of few nanometers and a specific surface area of 996 m2 g–1 (MOF, metal–organic framework). Our models and experiments reveal that this electrically conductive microporous nanosheet architecture enables the reuse of polysulfide trapped in the membrane and decreases the polysulfide flux and concentration on the anode side by a factor of 250× over recent microporous membranes made of granular MOFs and standard battery separators. Notably, Li–S batteries using our Janus microporous membranes achieve an outstanding rate capability and long-term stability with 75.3% capacity retention over 1700 cycles. We demonstrate the broad applicability of our high-aspect-ratio MOF/graphene nanosheet preparation strategy by the synthesis of a diverse range of MOFs, including ZIF-67, ZIF-8, HKUST-1, NiFe-BTC, and Ni-NDC, providing a flexible approach for the design of Janus microporous membranes and electrically conductive microporous building blocks for energy storage and various other electrochemical applications.

2D materials possess wide-tuning properties ranging from semiconducting and metallization to superconducting, etc., which are determined by their structure, empowering them to be appealing in optoelectronic and photovoltaic applications. Pressure is an effective and clean tool that allows modifications of the electronic structure, crystal structure, morphologies, and compositions of 2D materials through van der Waals (vdW) interaction engineering. This enables an insightful understanding of the variable vdW interaction induced structural changes, structure-property relations as well as contributes to the versatile implications of 2D materials. Here, the recent progress of high-pressure research toward 2D materials and heterostructures, involving graphene, boron nitride, transition metal dichalcogenides, 2D perovskites, black phosphorene, MXene, and covalent-organic frameworks, using diamond anvil cell is summarized. A detailed analysis of pressurized structure, phonon dynamics, superconducting, metallization, doping together with optical property is performed. Further, the pressure-induced optimized properties and potential applications as well as the vision of engineering the vdW interactions in heterostructures are highlighted. Finally, conclusions and outlook are presented on the way forward.

Magnetism in two dimensions is one of the most intriguing and alluring phenomena in condensed matter physics. Atomically thin 2D materials have emerged as a promising platform for exploring magnetic properties, leading to the development of essential technologies such as supercomputing and data storage. Arising from spin and charge dynamics in elementary particles, magnetism has also unraveled promising advances in spintronic devices and spin-dependent optoelectronics and photonics. Recently, antiferromagnetism in 2D materials has received extensive attention, leading to significant advances in their understanding and emerging applications; such materials have zero net magnetic moment yet are internally magnetic. Several theoretical and experimental approaches have been proposed to probe, characterize, and modulate the magnetic states efficiently in such systems. This Review presents the latest developments and current status for tuning the magnetic properties in distinct 2D van der Waals antiferromagnets. Various state-of-the-art optical techniques deployed to investigate magnetic textures and dynamics are discussed. Furthermore, device concepts based on antiferromagnetic spintronics are scrutinized. We conclude with remarks on related challenges and technological outlook in this rapidly expanding field.

Stony coral morphology inspires ultra-stable sunlight absorber structure with highest reported absorptance for high-temperature solar thermal applications.

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Summary1. There is great interest among policy makers in the potential of carbon-based payments for ecosystem services (PES) to reduce carbon emissions from deforestation and protect forests in tropical countries. We discuss the contributions that ecologists can make to the interdisciplinary research required to inform the design of these initiatives. 2. First, we highlight the need to quantify the full range of processes that determine temporal variation in carbon stocks at a landscape-scale due to cycles of forest disturbance and recovery. Second, we discuss the importance of understanding how the impact of climate change on the carbon stocks of intact forests may affect the emissions reductions achieved by any given project: we show that this may reduce the effectiveness of one carbon-based PES project in southern Peru by 15%. We also discuss the need to assess project impacts on deforestation in the surrounding region and explore how different project designs influence the balance between the conservation of carbon and biodiversity. 3. The need to demonstrate emissions reductions or carbon storage to investors in carbon-based payment schemes provides an imperative for monitoring their effectiveness. Monitoring will be a significant cost in any PES project and, together with project set-up, on average accounts for more than 40% of project expenditure across six emerging Peruvian PES schemes. Ecologists will therefore have an important role in designing cost-effective monitoring strategies. The impetus for monitoring also provides opportunities to carry out research addressing many of the uncertainties highlighted above. 4. Synthesis and applications. By working closely with a range of carbon-based PES projects, ecologists can answer important fundamental questions related to the provision of ecosystem services and help improve the design of these schemes. The large number of projects currently being implemented provides an unprecedented opportunity to develop a proper evidence base for measuring and improving the practices that most successfully conserve tropical forest ecosystems.

We have developed a method to measure thermodiffusion and Fickian diffusion in transparent binary solutions. The measuring instrument consists of two orthogonally aligned phase-shifting interferometers coupled with a single rotating polarizer. This high-resolution interferometer, initially developed to measure isothermal diffusion coefficients in liquid systems [J. F. Torres, A. Komiya, E. Shoji, J. Okajima, and S. Maruyama, Opt. Lasers Eng. 50, 1287 (2012)], was modified to measure transient concentration profiles in binary solutions subject to a linear temperature gradient. A convectionless thermodiffusion field was created in a binary solution sample that is placed inside a Soret cell. This cell consists of a parallelepiped cavity with a horizontal cross-section area of 10 × 20 mm(2), a variable height of 1-2 mm, and transparent lateral walls. The small height of the cell reduces the volume of the sample, shortens the measurement time, and increases the hydrodynamic stability of the system. An additional free diffusion experiment with the same optical apparatus provides the so-called contrast factors that relate the unwrapped phase and concentration gradients, i.e., the measurement technique is independent and robust. The Soret coefficient is determined from the concentration and temperature differences between the upper and lower boundaries measured by the interferometer and thermocouples, respectively. The Fickian diffusion coefficient is obtained by fitting a numerical solution to the experimental concentration profile. The method is validated through the measurement of thermodiffusion in the well-known liquid pairs of ethanol-water (ethanol 39.12 wt.%) and isobutylbenzene-dodecane (50.0 wt.%). The obtained coefficients agree with the literature values within 5.0%. Finally, the developed technique is applied to visualize biomolecular thermophoresis. Two protein aqueous solutions at 3 mg∕ml were used as samples: aprotinin (6.5 kDa)-water and lysozyme (14.3 kDa)-water. It was found that the former protein molecules are thermophilic and the latter thermophobic. In contrast to previously reported methods, this technique is suitable for both short time and negative Soret coefficient measurements.