Co(x)Ni(1-x) alloy nanowires with varying Co content (0 ≤ x ≤ 0.95), having a diameter of 130 nm and length of around 20 μm, are synthesized by template-assisted electrodeposition into the nanopores of SiO(2) conformal coated hard-anodic aluminum oxide membranes. The magneto-structural properties of both single isolated nanowires and hexagonally ordered nanowire arrays of Co-Ni alloys are systematically studied by means of magneto-optical Kerr effect magnetometry and vibrating sample magnetometry, respectively, allowing us to compare different alloy compositions and to distinguish between the magnetostatic and magnetocrystalline contributions to the effective magnetic anisotropy for each system. The excellent tunable soft magnetic properties and magnetic bistability exhibited by low Co content Co-Ni nanowires indicate that they might become the material of choice for the development of nanostructured magnetic systems and devices as an alternative to Fe-Ni alloy based systems, being chemically more robust. Furthermore, Co contents higher than 51 at.% allow us to modify the magnetic behavior of Co-rich nanowires by developing well controlled magnetocrystalline anisotropy, which is desirable for data storage applications.
The edge sites of molybdenum disulfide (MoS 2 ) have been shown to be efficient electrocatalysts for the hydrogen evolution reaction (HER). To utilize these structures, two main strategies have been proposed. The first strategy is to use amorphous structures, which should be beneficial in maximizing the area of the edge-site moieties of MoS 2 . However, these structures experience structural instability during HER. The other strategy is nanostructuring, in which, to enhance the resulting HER performance, the exposed surfaces of MoS 2 cannot be inert basal planes. Therefore, MoS 2 may need critical nanocrystallinity to produce the desired facets. Here, we first describe that when atomic layer deposition (ALD) is applied to layered materials such as MoS 2 , MoS 2 exhibits the nonideal mode of ALD growth on planar surfaces. As a model system, the ALD of MoCl 5 and H 2 S was studied. This nonideality does not allow for the conventional linear relationship between the growth thickness and the number of cycles. Instead, it provides the ability to control the relative ratios of the edge sites and basal planes of MoS 2 to the exposed surfaces. The number of edge sites produced was carefully characterized in terms of the geometric surface area and effective work function and was correlated to the HER performance, including Tafel slopes and exchange current densities. We also discussed how, as a result of the low growth temperature, the incorporation of chlorine impurities affected the electron doping and formation of mixed 2H and 1T phases. Remarkably, the resulting 1T phase was stable even upon thermal annealing at 400 °C. With the simple, planar MoS 2 films, we monitored the resulting catalytic performance, finding current densities of up to 20 mA cm −2 at −0.3 V versus the reversible hydrogen electrode (RHE), a Tafel slope of 50−60 mV/decade, and an onset potential of 143 mV versus RHE.
Pores growth mechanism and their self-ordering conditions are investigated for nanoporous alumina membranes synthesized by hard anodization (HA) of Al in a broad range of anodic conditions, covering oxalic acid electrolytes with concentrations from 0.300 M down to 0.075 M and potentiostatic anodization voltages between 120 and 225 V. The use of linear sweep voltammetry (LSV) and scanning and transmission electron microscopy, together with image analysis techniques allow one to characterize the intrinsic nature of the HA regime. HA of aluminum is explained on the basis of a phenomenological model taking into account the role of oxalate ions and their limited diffusion through alumina nanochannels from a bulk electrolyte. The depletion of oxalate ions at the bottom of the pores causes an increased growth of the alumina barrier layer at the oxide/electrolyte interface. Furthermore, an innovative method has been developed for the determination of the HA conditions leading to self-ordered pore growth in any given electrolyte, thus allowing one to extend the available range of interpore distances of the highly ordered hexagonal pore arrangement in a wide range of 240-507 nm, while keeping small pore diameters of 50-60 nm.
Anodic alumina membranes with modulated pore diameters serve as template for the preparation of magnetic nanowires. Filling the pores with Ni by electrodeposition delivers wires replicating the variation in modulation in pore diameter from 80 to 160 nm. Such structures are of interest for the observation and control of magnetic domain wall motion. Single-object characterization utilizing the magneto-optical Kerr effect magnetometry evidences a strong correlation between geometric parameters and magnetic properties. Ensemble magnetization measurements with a superconducting quantum interference device show the effect of dipolar interactions. Analytical models can reproduce the lowering of coercivity due to the presence of enhanced stray fields within the array. Magnetic force microscopy at individual wires indicates the presence of a strong stray field in the vicinity of the diameter change. The preparation technique demonstrates a mass production method of nano-objects with designed geometric irregularities, which could be used to control the motions of magnetic domain walls.
A composite chalcogenide with bulk layered heterojunctions exhibits an excellent catalytic activity for hydrogen production.
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