We demonstrate a new optical approach to generate high-frequency (>15 MHz) and high-amplitude focused ultrasound, which can be used for non-invasive ultrasound therapy. A nano-composite film of carbon nanotubes (CNTs) and elastomeric polymer is formed on concave lenses, and used as an efficient optoacoustic source due to the high optical absorption of the CNTs and rapid heat transfer to the polymer upon excitation by pulsed laser irradiation. The CNT-coated lenses can generate unprecedented optoacoustic pressures of >50 MPa in peak positive on a tight focal spot of 75 μm in lateral and 400 μm in axial widths. This pressure amplitude is remarkably high in this frequency regime, producing pronounced shock effects and non-thermal pulsed cavitation at the focal zone. We demonstrate that the optoacoustic lens can be used for micro-scale ultrasonic fragmentation of solid materials and a single-cell surgery in terms of removing the cells from substrates and neighboring cells.

In addition to colorant-based pigmentation, structure is a major contributor to a material's color. In nature, structural color is often caused by the interaction of light with dielectric structures whose dimensions are on the order of visible-light wavelengths. Different optical interactions including multilayer interference, light scattering, the photonic crystal effect, and combinations thereof give rise to selective transmission or reflection of particular light wavelengths, which leads to the generation of structural color. Recent developments in nanofabrication of plasmonic and carbon nanostructures have opened another efficient way to control light properties at the subwavelength scale, including visible-light wavelength selection, which can produce structural color. In this Concept, the most relevant and representative achievements demonstrated over the last several years are presented and analyzed. These plasmonic and carbon nanostructures are believed to offer great potential for high-resolution color displays and spectral filtering applications.

The fabrication and characterization of hybrid architectures of ZnO nanowires (ZNWs) grown on organized carbon nanotubes (CNTs), by a two‐step chemical vapor deposition (CVD) process involving CNT growth from a hydrocarbon source followed by ZNW growth using a Zn metal source, is reported. The ZNWs grow uniformly and radially from individual CNTs and CNT bundles, and the aligned morphology of the CNTs is not disturbed by the ZNW growth process. The nucleation and growth of ZnO crystals on CNTs are analyzed in relation to the classical vapor–solid mechanism. Importantly, the CNTs make uniform and distributed electrical contact to the ZNWs, with up to a 1000‐fold yield advantage over conventional ZNW growth on a flat substrate. Hybrid ZNW/CNT sheets are fabricated by scalable CVD, rolling, and printing methods; and their electrical properties, which are governed by transport through the anisotropic CNT network, are characterized. Functional interaction between the ZNWs and CNTs is demonstrated by photoconductive behavior and photocurrent generation of the hybrid material under UV illumination. There is significant future opportunity to extend these processing methods to fabricate other functional oxides on CNTs, and to build devices that harness the attractive properties of ZNWs and CNTs with high volumetric efficiency over large areas.

A novel nanofabrication methodology for continuous, scalable, and geometry-tunable lithography is developed, named photo-roll lithography (PRL), by integrating photolithography with rollable processing. As a flexible mask attached to a quartz cylinder containing a UV source rolls over a photoresistcoated substrate, PRL realizes continuous photolithographic fabrication of various micro/nanoscale patterns with geometry that is tunable by controlling mask-substrate motions.

We demonstrate carbon nanotube ͑CNT͒ composite-based optoacoustic transmitters that generate strong and high frequency ultrasound. The composite consists of CNTs grown on a substrate, which are embedded in elastomeric polymer used as an acoustic transfer medium. Under pulsed laser excitation, the composite generates very strong optoacoustic pressure: 18 times stronger than a Cr film reference and five times stronger than a gold nanoparticle composite with the same polymer. This enhancement persists over a broadband frequency range of up to 120 MHz and is confirmed by calculation. We suggest the CNT-polymer composites as highly efficient optoacoustic transmitters for high resolution ultrasound imaging. © 2010 American Institute of Physics. ͓doi:10.1063/1.3522833͔Laser-induced ultrasound generation is an effective way to make high frequency ultrasound transmitters by exploiting the high frequency spectra of laser pulses to achieve broad acoustic bandwidths. Typically, such transmitters are made of light-absorbing thin films containing specific structures designed to have high optical absorption that are capable of efficient optoacoustic conversion, for example, thin metal, 1 dye-doped polymer composites, 2,3 and two-dimensional ͑2D͒ gold nanoparticle ͑AuNP͒ arrays. 4 They are often integrated with optical interferometric detectors ͑e.g., FabryPérot etalon͒ 5 to make all-optical ultrasound transducers working over broadband and high frequency in 2D array platforms. In these arrays, the size of each element was determined by the spot size of the focused laser beam that is of the order of several microns.Thin metallic coatings on solid substrates are suitable as a common reference material for qualifying the performance of optoacoustic transmitters.1,2 While these thin films ͑Ͻ1 m͒ can be used as high frequency ultrasound sources their optoacoustic conversion efficiency is poor mainly because of the low thermal expansion. Also, a significant percentage of light is reflected back from the film surface.As large thermal expansion is desirable for strong pressure generation, an elastomeric polymer, polydimethylsiloxane ͑PDMS͒, has been used as an acoustic transfer medium to interface with light-absorbers.2-5 A composite film of PDMS with carbon black as a light-absorber has shown nearly 20 dB improvement in optoacoustic signal strength as compared to a reference Cr film alone.2 However, high frequency response was severely limited due to the composite film thickness ͑ϳ25 m͒ due to the acoustic attenuation. This is a serious issue because high frequency performance is vital for optoacoustic transmitters. Moreover, it is challenging to obtain uniform mixing and dispersion of carbon black particles in the PDMS matrix. Agglomeration of carbon black can cause uneven light absorption within the same film. Significant progress has been recently made using a planar array of AuNPs with an overlying PDMS layer of several microns. 4 High frequency output was improved by ϳ5 dB over 70-100 MHz as compared with those carbon black-PDMS...

We demonstrate broadband, near perfect absorption with a conformal coating of a multi-walled carbon nanotube (CNT) forest on an arbitrarily shaped surface. The complex refractive index of such a CNT forest is retrieved from the measured transmission and reflection spectra using Kramers-Kronig constrained variational analysis, which gives a typical value of neff = 1.04 + 0.01i at visible wavelengths. Therefore, when used as a conformal coating on an object, a thick layer of the CNT forest can provide an excellent impedance match to air and near perfect absorption, preventing any detectable light reflection and scattering from the object.

We have developed a novel fabrication method for flexible gas sensors for toxic gases based on sequential wet chemical reaction. In specific, zinc oxide (ZnO) nanowires were locally synthesized and directly integrated on a flexible polymer substrate using localized hydrothermal synthesis methods and their surfaces were selectively functionalized with palladium (Pd) nanoparticles using a liquid phase deposition process. Because the entire process is conducted at a low temperature in a mild precursor solution, it can be applied for flexible substrates. Furthermore, the surface of ZnO nanowires was sulfurized by hydrogen sulfide (H2S) gas to form zinc oxide/zinc sulfide (ZnO/ZnS) core–shell nanowires for stable sensing of H2S gas. The locally synthesized ZnO/ZnS core–shell nanowires enable an ultracompact-sized device, and Pd nanoparticles improve the sensing performance and reduce the operating temperature (200 °C). The device shows a high sensitivity [(G gas – G air)/G air × 100% = 4491% to 10 ppm], fast response (response/recovery time <100 s) to hydrogen sulfide, and outstanding selectivity (>100 times) to other toxic gases (e.g., carbon monoxide, acetone, ethanol, and toluene). Moreover, vertically synthesized nanowires provide a long bending path, which reduces the mechanical stresses on the structure. The devices showed stable gas sensing performance under 9 mm positive radius of curvature and 5 mm negative radius of curvature. The mechanical robustness of the device was also verified by numerical simulations which showed dramatic decrease of maximum stress and strain to 4.2 and 5.0%, respectively.

We demonstrate the continuous fabrication of large-area flexible metamaterial films via roll-to-roll (R2R) nanoimprint lithography (NIL) technique that can be conducted in an ambient environment at high speed. The plasmonic metal-insulator-metal structure is successfully fabricated by R2R NIL to continuously pattern the sub-wavelength scale metal disk array on flexible substrates. The patterned metal disks having varying diameters and sub-micron spacing with few defects lead to the desired broadband IR filtering performance at the designed dual-band, which correlates well with simulation analysis. Our method realizes a simple and high-throughput fabrication of plasmonic metamaterials for scalable and flexible optoelectronic and photonic applications.