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Although Earth has a convecting mantle, ancient mantle reservoirs that formed within the first 100 Ma of Earth’s history (Hadean Eon) appear to have been preserved through geologic time. Evidence for this is based on small anomalies of isotopes such as182W,142Nd, and129Xe that are decay products of short-lived nuclide systems. Studies of such short-lived isotopes have typically focused on geological units with a limited age range and therefore only provide snapshots of regional mantle heterogeneities. Here we present a dataset for short-lived182Hf−182W (half-life 9 Ma) in a comprehensive rock suite from the Pilbara Craton, Western Australia. The samples analyzed preserve a unique geological archive covering 800 Ma of Archean history. Pristine182W signatures that directly reflect the W isotopic composition of parental sources are only preserved in unaltered mafic samples with near canonical W/Th (0.07 to 0.26). Early Paleoarchean, mafic igneous rocks from the East Pilbara Terrane display a uniform pristine µ182W excess of 12.6 ± 1.4 ppm. Fromca. 3.3Ga onward, the pristine182W signatures progressively vanish and are only preserved in younger rocks of the craton that tap stabilized ancient lithosphere. Given that the anomalous182W signature must have formed byca. 4.5 Ga, the mantle domain that was tapped by magmatism in the Pilbara Craton must have been convectively isolated for nearly 1.2 Ga. This finding puts lower bounds on timescale estimates for localized convective homogenization in early Earth’s interior and on the widespread emergence of plate tectonics that are both important input parameters in many physical models.

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Significance Due to active plate tectonics, there are no direct rock archives covering the first ca. 500 million y of Earth’s history. Therefore, insights into Hadean geodynamics rely on indirect observations from geochemistry. We present a high-precision 182 W dataset for rocks from the Kaapvaal Craton, southern Africa, revealing the presence of Hadean protocrustal remnants in Earth’s mantle. This has broad implications for geochemists, geophysicists, and modelers, as it bridges contrasting 182 W isotope patterns in Archean and modern mantle-derived rocks. The data reveal the origin of seismically and isotopically anomalous domains in the deep mantle and also provide firm evidence for the operation of silicate differentiation processes during the first 60 million y of Earth’s history.

Numerous supracrustal belts in southern West Greenland host leucoamphibolites, which commonly preserve volcaniclastic textures, and are interpreted as meta-andesites. Such rocks are associated with mesocratic amphibolites of tholeiitic basaltic compositions, which display pillow-lava structures and, thus, support eruption in an oceanic environment. Here we present bulk-rock Lu–Hf isotope data for meta-andesites from the approximately 3071 Ma Qussuk supracrustal belt. Surprisingly, we find evidence for the involvement of a source with near-chondritic Hf-isotope composition in the meta-andesites, whereas the metabasalts display more depleted compositions, with around +4. Trace element modelling indicates that fractional crystallization in combination with crustal assimilation (AFC) is not capable of producing the geochemical compositions of the meta-andesitic rocks from a basaltic melt. Instead, these meta-andesites point to large degrees (c. 50%) of magma mixing, involving mafic and felsic end members. This may either represent: (1) a magma chamber process; (2) mantle-wedge overprinting by a silicic component; or (3) large degrees of melting of primitive mafic crust. Given that there is abundant independent structural and metamorphic evidence for horizontal tectonics in the Archaean crust of southern West Greenland, it is likely that these calc-alkaline meta-andesites and tholeiitic metabasalts were produced by Mesoarchaean subduction zone volcanism.