2022
DOI: 10.1073/pnas.2120241119
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Long-term preservation of Hadean protocrust in Earth’s mantle

Abstract: Significance Due to active plate tectonics, there are no direct rock archives covering the first ca. 500 million y of Earth’s history. Therefore, insights into Hadean geodynamics rely on indirect observations from geochemistry. We present a high-precision 182 W dataset for rocks from the Kaapvaal Craton, southern Africa, revealing the presence of Hadean protocrustal remnants in Earth’s mantle. This has broad implications for geochemists, geophysicists, and modeler… Show more

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Cited by 23 publications
(28 citation statements)
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“…In-house rock reference material LP 1 is a historical OIB from La Palma (erupted 1480), AGC 351 is a 3455 Ma old granitic gneiss from the Kaapvaal Craton, Southern Africa 45 and 160245 is a 3270 Ma old Komatiite from the Pilbara Craton, NW Australia 11 . The W isotope composition for Cologne in-house rock reference materials reported in this study overlaps with the long-term average that has previously been obtained to assess the intermediate precision for W isotope composition analysis at University of Cologne (Supplementary Data 2 ) 11 , 40 , 41 .…”
Section: Methodssupporting
confidence: 74%
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“…In-house rock reference material LP 1 is a historical OIB from La Palma (erupted 1480), AGC 351 is a 3455 Ma old granitic gneiss from the Kaapvaal Craton, Southern Africa 45 and 160245 is a 3270 Ma old Komatiite from the Pilbara Craton, NW Australia 11 . The W isotope composition for Cologne in-house rock reference materials reported in this study overlaps with the long-term average that has previously been obtained to assess the intermediate precision for W isotope composition analysis at University of Cologne (Supplementary Data 2 ) 11 , 40 , 41 .…”
Section: Methodssupporting
confidence: 74%
“…All studied Temagami BIF samples show positive 182 W offsets up to ~8 ppm compared to the inferred modern BSE value, suggesting an average positive µ 182 W signature of the total global W flux into the ocean at 2.7 Ga. With the exception of samples from the southern African region 14 , 39 , 40 , previously studied Archean rocks, irrespective of rock type, are characterized by positive µ 182 W compositions 4 , 5 , 12 , 13 , 41 (Supplementary Fig. 1 ).…”
Section: Resultsmentioning
confidence: 86%
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“…Conversely, only samples with MORB-like W/Th may preserve the W isotope composition of their original magmatic source. Within the μ 182 W data set from the Kaapvaal Craton, only four samples exhibit MORB-like W/Th ratios (Tusch et al, 2022;this study). None of these samples show clearly resolvable W isotope anomalies (average μ 182 W = −2.2 ± 2.4), indicating that negative μ 182 W values are not intrinsic to the magmatic sources of analyzed volcanic rocks of the Craton.…”
Section: The Tungsten Budget Of Volcanic Rocks From the Kaapvaal And ...mentioning
confidence: 74%
“…Mundl et al 2017;Willbold et al 2011) has been suggested to imply inefficient mixing between Earth and the moon-forming impactor and, hence, speak against a planetary-mass impactor. However, the small 182 W deficits identified in modern deep-seated mantle plumes are thought to reflect interaction with Earth's core whereas the 182 W excesses measured in Archean rocks (Mundl-Petermeier et al 2020;Rizo et al 2019) are interpreted to reflect the composition of Earth's mantle prior to the addition of the late veneer (Willbold et al 2011;Tusch et al 2021). As such, the preservation of 182 W heterogeneities in Earth's deep mantle does not provide evidence for limited mixing during the moon-forming impact.…”
Section: Discussionmentioning
confidence: 99%