Dry reforming is a very interesting process for synthesis gas generation from CH 4 and CO 2 but suffers from low hydrogen yields due to the reverse water-gas shift reaction (WGS). For this reason, membranes are often used for hydrogen separation, which in turn leads to coke formation at the process temperatures suitable for the membranes. To avoid these problems, this work shows the possibility of using nickel self-supported membranes for hydrogen separation at a temperature of 800 • C. The higher temperature effectively suppresses coke formation. The paper features the analysis of the dry reforming reaction in a nickel membrane reactor without additional catalyst. The measurement campaign targeted coke formation and conversion of the methane feedstock. The nickel approximately 50% without hydrogen separation. The hydrogen removal led to an increase in methane conversion to 60-90%.
Targeting transient operation of high temperature solid oxide cell (SOC) systems this paper proposes an enhanced heat management mechanism using planar high temperature heat pipes that can be integrated into the SOC‐stack structure. Flat heat pipes with thicknesses down to 4 mm filled with liquid alkali metals for almost isothermal 2D heat spreading, even for intense heat transfer rates, are demonstrated. A new pathway towards a temperature gradient shrinking in SOC‐stacks without using large amounts of additional air‐cooling is shown. The paper will present latest development results on design concepts, size reduced fabrication and filling procedure. An experimental study demonstrates the heat spreading capabilities and power limitations of planar heat spreaders for high temperature applications as in SOEC/SOFC stacks.
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