or adsorption onto the smallest particles is proposed to account for the trace element concentration dependence on particle size. The environmental significance of the results is discussed.

The toxic trace elements arsenic, antimony, cadmium, lead, selenium, and thallium were found to be most concentrated in the smallest respirable particles emitted from coal-fired power plants. These elements, or their compounds, are probably volatilized during combustion and preferentially adsorb or condense onto the small particles which can most easily pass through conventional control equipment.

The basic thesis developed herein is that particle size is an extremely important parameter to consider when assessing the potential toxicity of species present in urban aerosols, and that surface adsorption or condensation greatly promotes toxicity. In the majority of cases this means that particles that are less than 1 micro.m in size are of primary importance. Special significance is attached to the organic constitutents of aerosols. Many of these are known or potential carcinogens and most predominate in extremely small particles which become deposited almost exclusively in the lung.

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