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A summary of recent observations of the properties of ZnS:Cu:Pb and ZnS:Cu:Pb:Mn electroluminescent phosphors is reported. The experiments include studies of the optical and electrical response of these phosphors dispersed in "Lucite" to sudden changes in a constant applied field, as well as microscopic studies of the luminescence of individual particles. Both green and yellow phosphors were studied. The most important results observed primarily on green phosphors are the following: Slow changes are found to take place in a phosphor in any given constant electric field, but a steady state is finally approached. A sudden departure from this state produced by changing the applied field will in general produce very little light compared to that produced on returning promptly to the conditions under which the steady state was established. Further, the luminescence in alternating electric fields of individual grains is extremely inhomogeneous, being restricted to small "pinpoints" or "spots" very much smaller than the individual particles. The spots studied luminesced only once per cycle.It is concluded that excitation of luminescent centers occurs primarily by ionization, with recombination and radiation occurring when subsequent electrical changes make this possible. Although excitation of luminescent centers to bound states followed by prompt radiation does occur, under the conditions of these experiments this process is of secondary importance in producing light in all the phosphors studied, and is quite negligible in the green phosphors. These and other results are discussed in connection with the several possible mechanisms by which electric fields may bring about the excitation of luminescent centers.

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Indications from voltage-current curves of thermionic power converters suggest increased ionization at, or very near, cesium-coated surfaces by low-energy electrons. Experiments have been conducted to study this phenomenon quantitatively for a low cesium concentration. The tube contained three indirectly heated tantalum surfaces surrounded by a shield. These heated surfaces, El, E2, and E3, were tantalum tubes located at the three corners of an equilateral triangle. The extension of a line from the corner EL perpendicular to the base of the triangle formed by the line E2 and E3 served to locate the position of a fine-wire ion collector. Electrons were accelerated from surfaces E2 and E3 to bombard El. Ions produced at or near El were then accelerated toward the ion collector to serve as a measure of the ion production. Results of this experiment indicate that no appreciable ion current was produced in cesium vapor controlled by a TCs = 350°K, by electrons having an energy less than 3.89 volts. The square root of the ion-to-electron current ratio was a linear function of the surface electron energy in excess of the ionization potential. Although not accurately determined, the ionization coefficient is given by Pi = P (V-Vl) with P1 = 20 cm v for the standard condition of 3.54 X 1016 atoms/cm 3 II. The Energy Distribution for Electrons in a Thermionic Diode Plasma Cannot Be Truly Maxwellian AbstractFor the refractory emitters, such as tungsten, tantalum, and molybdenum, operated in an energy-conversion diode, the ratio of the emitter temperature to the cesium temperature strongly influences the operating properties. If this ratio exceeds 3. 2, an ionrich sheath usually forms at the emitter surface. Electrons are accelerated in the plasma space by this injection potential. An analysis made here shows that at the opencircuit condition, the energy distribution of the electrons at the plasma edge of the emitter sheath cannot be a true Maxwellian over the entire range in electron energy. Instead, it is thought to be made up of two quasi-Maxwellians. The low-energy electrons are trapped and may have a high average energy close to that of the injection potential. The untrapped electrons will have an electron temperature equal to that of the emitter and their density will be that associated with an apparent or fictitious density many times that of the actual density.A theory has been developed to describe quantitatively the relations that must be satisfied for the description above to apply. From typical numerical results that are applicable to specific diode configurations it is concluded that if the emitter-to-cesium temperature ratio exceeds 3.6, volume ionization is not required for a stable sheath. In the range 3.2-3. 6 surface ionization is usually insufficient, and it is necessary to have volume ionization to sustain the sheath. Further studies will be required to establish the mechanism. It may be direct ionization by high-energy electrons, or ionization from excited states of the cesium atoms.

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