This study aims to analyze whether ammonia emission occurs when municipal solid waste (MSW) is incinerated. In cases where ammonia is emitted, we aim to develop an emission factor, calculate annual emission amounts by utilizing activity data (waste incineration amount) applied in air pollutant emission calculations for the waste combustion in Korea, and investigate whether there is a need for emission calculation. As a result of the study, the ammonia emission factor of the MSW incineration facility to be studied was 0.0091 kgNH3/ton, which was 3 times higher than the emission factor in Europe. In the case of emissions, a randomly developed emission factor was applied to confirm the necessity of development of the emission factor, and as a result of the application, it was found to be 22 NH3 ton/year, which is the same number as the annual NH3 emission of the entire waste treatment sector in 2016. Therefore, we believe that MSW incinerator facilities should be recognized as one of the major NH3 omitted emission sources. Moreover, it is evident that there is a need for an NH3 emission factor and emission calculations that reflect the characteristics of Korea.
Biomass burning is largely divided into six types: open burning, agricultural waste burning, meat and fish roasts, wood stoves and boilers, furnaces, and charcoal burners. Biomass burning is largely characterized by incomplete combustion due to the difficulty of appropriate control, which results in the emission of a large amount of air pollutants and the generation of harmful substances such as volatile organic compounds (National Institute of Environmental Research, 2014). Burning agricultural residue releases a large amount of fine particulate matter (PM). Open burning of agricultural residue, burning agricultural residues without incineration facility, in the rural areas are frequently observed Therefore, management based on accurate analysis of emission characteristics is needed. In Korea, most agricultural residues except for rice straw are incinerated in the field. Agricultural residues with a high incineration ratio are Chili and Perilla. The characteristics of PM emission by agricultural residues combustion were analyzed for Chili and Perilla. PM measuring equipment are Stack sampling system and Cascade Impactor (PM10, PM2.5 Impactor, Johnas, Paul Gothe GmBH). This study, the emission characteristics of PM-10, PM-2.5 generated in the combustion of agricultural residues were examined in consideration of moisture content.
Ammonia is a representative PM-2.5 secondary product, and the need for management is emerging as health and living damage caused by fine particulate matter worsens. The main source of ammonia is the agricultural sector, and in Korea, 79% of the total ammonia emissions are emitted from the agricultural sector. Among them, there is high uncertainty about how to calculate emissions from ammonia discharged from fertilizer use, and inventory in the U.S. and Europe is borrowed, so inventory needs to be improved according to the situation in Korea. In this study, the ammonia inventory in the agricultural sector in Korea and abroad was examined, and additional activity data that can be used were reviewed. In addition, in order to improve the emission calculation method, the emission was calculated in three ways by different factors. As a result, it was confirmed that the amount of discharge varies depending on the type of soil use or whether cultivated crops are considered, and the possibility of excessive fertilizer top-dress by farmers was confirmed. In order to calculate the emission at a more detailed level based on this study, basic data such as fertilizer input method and regional distribution of crops should be systematically collected, and related follow-up studies should be conducted.
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