This paper is mainly aimed at the problem of low bonding strength of soy bean protein adhesive,poor water resistance,with methyl methacrylate and vinyl acetate composite study made with rubber manufacturing class II plywood,meet the national standard,so as to solve the water resistance of soy protein adhesives and bonding strength of.Experiments that 3.5g soy protein, 5g PVA, 30g MMA, 0.3g APS and 100g water, modified soy protein adhesive bonding strength obtained is excellent, and cost reduction.Preparation of soybean protein-acrylate adhesive solid content,viscosity and strength of plywood detection.
As the main adhesive types in wood-based panel industry,urea-formaldehyde has such shortcomings as high levels of free formaldehyde content and formaldehyde emission of its bonding product. In this experiment, we try to modify urea-formaldehyde resin with keratin through copolymerization reaction. Through the determination of such reaction technology as molar ratio, adding sequence of keratin and adding amount of keratin, we finally synthesized the low toxic urea resin. The results show that the optimum molar ratio is 1.3:1, the adding amount of keratin is 5% and adding keratin after the third feeding of urea is the best choice. By optimizing the synthesis process, we ultimately get the low toxicity modified urea-formaldehyde resin. At the same time, modified urea-formaldehyde resin cost has been reduced because extensive sources of keratin and low cost.
This study focuses on the manufacturing process of veneer composite plank and test the mechanical properties.The results showed that: ① In the dipping process, when the dipping time was 20min and adhesive solids was 25%,the veneer composite plank can get a better mechanical properties; ②In the low-temperature drying process, according to the mechanical properties and drying efficiency, low drying temperature appropriate select 50°C; ③Considering the mechanical properties and the cost issue as the density increases, select the density of 1.0g/cm3 is appropriate. Prove that the production technology is feasible, its products have uniform texture and good mechanical properties can be widely used for furniture, flooring and structural materials and other fields.
The main purpose of determining excellent performance of the system of emulsion through the chemical methods (MATS surface treatment)on soy-protein chemically modified, add a small amount of coupling agent as a horizontal cross-linker, and further enhance its water resistance and the strength of cement, in order to higher requirements. Research will be used description the solid content etc. of polymerization process used measure weight、viscosity etc., and analysis of particle structure and shape by TEM, SEM, analysis the surface properties of particles by FTIR, and ascertain by measuring adhesion properties of different emulsion on the same substrate by strength capability.
Corn straw was used as the main raw material, rice husk, peanut shell and sawdust were used as auxiliary materials; First using qualitative analysis method determined the samples of moisture, ash content, volatile matter, calorific value and the content of cellulose, hemicellulose lignin. Secondly in sulfuric acid as catalyst, ethylene glycol as liquefied agent, ethanol as auxiliary liquefied conditions, corn straw is liquefied. On this basis, single factor experiment was used to investigate the effects of reaction time, reaction temperature, catalyst dosage and liquefied agent on the liquefaction reaction. The experiment results show that reaction temperature is 250°C, reaction time is 2h, dosage of sulfuric acid is 2.9%, the liquefaction rate is 80%. And infrared spectrum analysis of liquefied products and scraps show that lignin, cellulose and hemicellulose have been broken down into different components, and two liquefaction are joined at the same time, the corn straw happen two different reactions.
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