Carbon nanotubes (CNTs)-based composites have attracted significant research interest in recent years, owing to their important applications in various technological fields. In this investigation, we describe a general approach to make CNTs-based nanocomposites via self-assembly. The method allows one to prepare binary composites as well as complex systems such as ternary or even quaternary composites where nanoparticles of active phases (e.g., metals and metal oxides) are used as primary building blocks. Six different kinds of binary, ternary, and quaternary nanocomposites, TiO2/CNTs, Co3O4/CNTs, Au/CNTs, Au/TiO2/CNTs, TiO2/Co3O4/CNTs, and Co/CoO/Co3O4/CNTs, have been reported herein in order to draw common features for various assembly schemes. To understand the interconnectivity between the active phases and CNTs, we have devised a range of experiments and examined the resultant samples with many instrumental techniques. On the basis of this work, we demonstrate that highly complex inorganic-organic nanohybrids with good controls in particle shape, size, and distribution can be fabricated from presynthesized nanobuilding units. Concerning their workability, we further show that self-assembled TiO2/CNTs are sufficiently robust and the electrochemical performance of TiO2 is significantly enhanced when it is used as a cathode material in Li-battery application.
The Ag/graphene heterostructures were synthesized through a simple thermal reduction process. The interaction between Ag nanoparticles and graphene supports along with the sur-
The graphite nanoplatelets (GNP) were treated by vapor-phase bromination. The increase in weight and atomic concentration of Br indicated the bromine uptake. The intercalation of Br between graphene layers of GNP was confirmed by the X-ray diffraction result, showing an increase in the interlayer spacing from 3.342 Å to 3.361 Å. Two types of bonds between C and Br were introduced simultaneously, ionic and covalent bonds, both of them increased with bromination duration. The fraction of ionic bond reached the highest value by 3 h Br exposure, which corresponded to the highest electrical conductivity of GNP. Although the bromination treatment did not change the percolation threshold of composites, it increased the absolute value of electrical conductivity of composites when the filler content was higher than the percolation threshold.
A modular and efficient method for the synthesis of α-substituted 1,2-dihydroquinolines is described. Under mild metal-free conditions, readily available N-carbamoyl 1,2-dihydroquinolines undergo oxidative C-H alkynylation, alkenylation, and allylation with a range of potassium trifluoroborates using TEMPO oxoammonium salt as an oxidant.
Porous carbons integrated with high gravimetric/volumetric/areal capacitances, especially at high mass loadings (>10 mg cm−2), are important for practical applications in supercapacitors. Here, a strategy is developed for the synthesis of ultramicroporous carbons puzzled by graphene quantum dots as the building units through chemical welding and in situ activation. The resulted carbon has unique ultramicroporous structure (≈0.5 nm) with both high surface area (1730 m2 g−1) and packing density (0.97 g cm−3), providing high gravimetric and volumetric capacitances of 270 F g−1 and 262 F cm−3 at 1 A g−1, respectively. More importantly, such carbon achieves an ultrahigh areal capacitance of 5.70 F cm−2 with a high mass loading of 25 mg cm−2 at 1 A g−1, which is one of the best among the previously reported porous carbons. Furthermore, a two‐electrode supercapacitor exhibits an ultrahigh areal capacitance of 3 F cm−2 at 0.5 A g−1, rapid charge–discharge ability, and long lifespan. This work paves an avenue for developing advanced porous carbons with integrated capacitive performances for supercapacitors.
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