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Novel Bi(2)S(3)/BiOI heterostructures were successfully synthesized through a facile and economical ion exchange method between BiOI and thioacetamide (CH(3)CSNH(2)), and characterized by multiform techniques, such as XRD, Raman, FT-IR, XPS, SEM, TEM, HRTEM, SAED, BET and DRS. The obtained Bi(2)S(3)/BiOI photocatalysts showed excellent photocatalytic performance for decomposing organic dye methyl orange (MO) compared with pure BiOI under visible light irradiation (λ > 420 nm). Among the Bi(2)S(3)/BiOI photocatalysts with different molar percentage of Bi(2)S(3) to initial BiOI (from 2 to 8%), 4% Bi(2)S(3)/BiOI exhibited the highest photocatalytic activity with apparent k(app) of 0.2968 h(-1). Differently, Bi(2)S(3)/BiOI displayed low photocatalytic activity for many colorless organic substrates, such as phenol, 2-chlorophenol, dimethyl phthalate and 5-sulfosalicylic acid. Moreover, the study on the mechanism suggested that the enhanced photocatalytic activity mainly resulted from the role of Bi(2)S(3)-BiOI heterojunctions formed in the Bi(2)S(3)/BiOI, which could lead to efficient separation of photoinduced carriers.

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