In this work, new lignin-based flame retardant LHDs were successfully synthesized through the reaction between lignin, 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) and hexamethylene diisocyanate (HDI).
In this study, a type of all‐degradable flame retardant wood/poly(lactic acid) (PLA) biocomposite (FPW) with low cost and excellent mechanical properties is prepared and studied. A novel lignin‐based phosphorus‐containing flame retardant (LMD) is synthesized first. PLA, wood powder, poly(butyleneadipate‐co‐terephthalate), triglycidyl isocyanurate (TGIC), and LMD are then melt‐blended to prepare FPW. The limiting oxygen index value of PLAF25L15‐4T (25% of L15MD and 4% of TGIC) reaches 28.6%. Furthermore, the residue at 700 °C is up to 31.3%, which apparently helps to increase the flame retardancy of FPW. Its tensile strength is as high as 48.7 MPa. The interfacial compatibilization is much improved as proved by scanning electron microscopy observation. This should be due to the in situ interfacial reaction between PLA, wood, and TGIC, and the lignin component both in wood and LMD. The obtained PLA biocomposite with improved mechanical and flame retardant properties is promising for its wide applications.
Improving the dimensional thermal stability and electrochemical performance of polyethylene (PE) membrane is critical to enhance the safety performance of lithium-ion battery. In this paper, PE membranes are modified by lithium bis(trifuoromethanesulfonyl)imide (LiTFSI) solution and then coated with nano-SiO 2 /polyvinyl alcohol solution to obtain composite membranes (PE@LnSiO 2 , where n represents the concentration of LiTFSI solution). The obtained PE@L4SiO 2 (LiTFSI solution concentration is 4%) composite membrane possesses a thermal shrinkage rate of only 17% at 150°C, which is far superior to that of the PE separator. The ionic conductivity of the composite membrane is 16.9 × 10 −4 S cm −1 at room temperature (RT), and the battery impedance decreases to 154 , which is remarkably better than that of the PE membrane (188 ). The battery delivers a reversible discharge capacity of 164 mAh g −1 at 0.2 C under RT after 250 cycles, and the coulomb efficiency remains above 99%. The battery also has a high discharge capacity of 132 mAh g −1 at 2 C, which indicates that it has excellent rate performance. Therefore, this research successfully explores a simple method to effectively improve the dimensional thermal stability of PE separator, as well as the electrochemical and safety performance of lithium battery.
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