As a flexible power source, energy storage has many potential applications in renewable energy generation grid integration, power transmission and distribution, distributed generation, micro grid and ancillary services such as frequency regulation, etc. In this paper, the latest energy storage technology profile is analyzed and summarized, in terms of technology maturity, efficiency, scale, lifespan, cost and applications, taking into consideration their impact on the whole power system, including generation, transmission, distribution and utilization. The application scenarios of energy storage technologies are reviewed and investigated, and global and Chinese potential markets for energy storage applications are described. The challenges of large-scale energy storage application in power systems are presented from the aspect of technical and economic considerations. Meanwhile the development prospect of global energy storage market is forecasted, and application prospect of energy storage is analyzed.
Aprotic Li–O2 batteries are regarded as the most promising technology to resolve the energy crisis in the near future because of its high theoretical specific energy. The key electrochemistry of a nonaqueous Li–O2 battery highly relies on the formation of Li2O2 during discharge and its reversible decomposition during charge. The properties of Li2O2 and its formation mechanisms are of high significance in influencing the battery performance. This review article demonstrates the latest progress in understanding the Li2O2 electrochemistry and the recent advances in regulating the Li2O2 growth pathway. The first part of this review elaborates the Li2O2 formation mechanism and its relationship with the oxygen reduction reaction/oxygen evolution reaction electrochemistry. The following part discusses how the cycling parameters, e.g., current density and discharge depth, influence the Li2O2 morphology. A comprehensive summary of recent strategies in tailoring Li2O2 formation including rational design of cathode structure, certain catalyst, and surface engineering is demonstrated. The influence resulted from the electrolyte, e.g., salt, solvent, and some additives on Li2O2 growth pathway, is finally discussed. Further prospects of the ways in making advanced Li–O2 batteries by control of favorable Li2O2 formation are highlighted, which are valuable for practical construction of aprotic lithium–oxygen batteries.
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