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A measurement of electron antineutrino oscillation by the Daya Bay Reactor Neutrino Experiment is described in detail. Six 2.9-GWth nuclear power reactors of the Daya Bay and Ling Ao nuclear power facilities served as intense sources of ν e 's. Comparison of theν e rate and energy spectrum measured by antineutrino detectors far from the nuclear reactors (∼1500-1950 m) relative to detectors near the reactors (∼350-600 m) allowed a precise measurement ofν e disappearance. More than 2.5 millionν e inverse beta-decay interactions were observed, based on the combination of 217 days of operation of six antineutrino detectors (December, 2011-July, 2012) with a subsequent 1013 days using the complete configuration of eight detectors (October, 2012-July, 2015. Theν e rate observed at the far detectors relative to the near detectors showed a significant deficit, R ¼ 0.949 AE 0.002ðstatÞAE 0.002ðsystÞ. The energy dependence ofν e disappearance showed the distinct variation predicted by neutrino oscillation. Analysis using an approximation for the three-flavor oscillation probability yielded the flavor-mixing angle sin 2 2θ 13 ¼ 0.0841 AE 0.0027ðstatÞ AE 0.0019ðsystÞ and the effective neutrino mass-squared difference of jΔm 2 ee j ¼ ð2.50 AE 0.06ðstatÞ AE 0.06ðsystÞÞ × 10 −3 eV 2 . Analysis using the exact three-flavor probability found Δm

Reactor neutrino experiments play a crucial role in advancing our knowledge of neutrinos. A precise measurement of reactor electron antineutrino flux and spectrum evolution can be key inputs in improving the knowledge of neutrino mass and mixing as well as reactor nuclear physics and searching for physics beyond the standard model. In this work, the evolution of the flux and spectrum as a function of the reactor isotopic content is reported in terms of the inverse-beta-decay yield at Daya Bay with 1958 days of data and improved systematic uncertainties. These measurements are compared with two signature model predictions: the Huber-Mueller model based on the conversion method and the SM2018 model based on the summation method. The measured average flux and spectrum, as well as their evolution with the 239 Pu isotopic fraction, are inconsistent with the predictions of the Huber-Mueller model. In contrast, the SM2018 model is shown to agree with the average flux and its evolution but fails to describe the energy spectrum. Altering the predicted IBD spectrum from 239 Pu fission does not improve the agreement with the measurement for either model. The models can be brought into better agreement with the measurements if either the predicted spectrum due to 235 U fission is changed or the predicted 235 U, 238 U, 239 Pu, and 241 Pu spectra are changed in equal measure.

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Herein, a new route was presented to synthesize 2-benzimidazolones via the carbonylation of o-phenylenediamines with CO2 catalyzed by 1,8-diaza­bicyclo­[5.4.0]­undec-7-ene (DBU)-based ionic liquids under solvent-free conditions. DBU acetate ([DBUH]­[OAc]) displayed high efficiency for catalyzing the reactions of CO2 with o-phenylenediamines, and a series of benzimidazolones were obtained in high yields. It was demonstrated that [DBUH]­[OAc] could serve as a bifunctional catalyst for these reactions with the cation activating CO2 and the anion activating o-phenylenediamines. This protocol provides an effective and environmentally friendly alternative route for production of benzimidazolones, and extends the chemical utilization of CO2 in organic synthesis as well.

The Daya Bay experiment was the first to report simultaneous measurements of reactor antineutrinos at multiple baselines leading to the discovery ofν e oscillations over km-baselines. Subsequent data has provided the world's most precise measurement of sin 2 2θ 13 and the effective mass splitting ∆m 2 ee . The experiment is located in Daya Bay, China where the cluster of six nuclear reactors is among the world's most prolific sources of electron antineutrinos. Multiple antineutrino detectors are deployed in three underground water pools at different distances from the reactor cores to search for deviations in the antineutrino rate and energy spectrum due to neutrino mixing. Instrumented with photomultiplier tubes, the water pools serve as shielding against natural radioactivity from the surrounding rock and provide efficient muon tagging. Arrays of resistive plate chambers over the top of each pool provide additional muon detection. The antineutrino detectors were specifically designed for measurements of the antineutrino flux with minimal systematic uncertainty. Relative detector efficiencies between the near and far detectors are known to better than 0.2%. With the unblinding of the final two detectors' baselines and target masses, a complete description and comparison of the eight antineutrino detectors can now be presented. This paper describes the Daya Bay detector systems, consisting of eight antineutrino detectors in three instrumented water pools in three underground halls, and their operation through the first year of eight detector data-taking.

The selective oxidation of glycerol was investigated using AuPd/ TiO 2 as the catalyst in the presence of AlCl 3 , and lactic acid was obtained as the predominant product. It was demonstrated that AuPd/TiO 2 and AlCl 3 played synergistic roles in the production of lactic acid. The possible reaction pathway was proposed, in which glycerol was first oxidized to glyceraldehyde and dihydroxyacetone, catalysed by AuPd/TiO 2 , followed by the formation of lactic acid, catalyzed by AlCl 3 .