Although various catalytic materials have emerged for hydrogen evolution reaction (HER), it remains crucial to develop intrinsically effective catalysts with minimum uses of expensive and scarce precious metals. Metallic glasses (MGs) or amorphous alloys show up as attractive HER catalysts, but have so far limited to material forms and compositions that result in high precious‐metal loadings. Here, an Ir25Ni33Ta42 MG nanofilm exhibiting high intrinsic activity and superior stability at an ultralow Ir loading of 8.14 µg cm−2 for HER in 0.5 m H2SO4 is reported. With an overpotential of 99 mV for a current density of 10 mA cm−2, a small Tafel slope of 35 mV dec−1, and high turnover frequencies of 1.76 and 19.3 H2 s−1 at 50 and 100 mV overpotentials, the glassy film is among the most intrinsically active HER catalysts, outcompetes any reported MG, representative sulfides, and phosphides, and compares favorably with other precious‐metal‐containing catalysts. The outstanding HER performance of the Ir25Ni33Ta42 MG film is attributed to the synergistic effect of the novel alloy system and amorphous structure, which may inspire the development of multicomponent alloys for heterogeneous catalysis.
Using both numerical and experimental methods, we studied the effect of coil configuration of pulsed magneto-oscillation (PMO) on distribution of electromagnetic field, flow field and solidification structure with the same pulse current parameters in Al ingots. We designed and constructed three types of coils: surface pulsed magneto-oscillation, hot-top pulsed magneto-oscillation (HPMO) and combined pulsed magneto-oscillation (CPMO). PMO treatment refined the solidification structure in all the ingots. The configuration of the PMO, however, introduced differences in magnetic field intensity, electromagnetic force, Joule heat, flow field, equiaxed grain zone, grain size and growth direction of columnar grains. The largest equiaxed grain zone was found in CPMO treated ingot, and the smallest grain size was found in both HPMO and CPMO treated ingots. Numerical simulation indicated that difference in electromagnetic field and flow field resulted in differences in solidification structure. HPMO is more advantageous over others for large ingot production.
General solutions to the quantum Rabi model involve subspaces with an unbounded number of photons. However, for the multiqubit multimode case, we find special solutions with at most one photon for an arbitrary number of qubits and photon modes. Such solutions exist for arbitrary single qubit-photon coupling strength with constant eigenenergy, while still being qubit-photon entangled states. Taking advantage of their peculiarities and the reach of the ultrastrong coupling regime, we propose an adiabatic scheme for the fast and deterministic generation of a two-qubit Bell state and arbitrary single-photon multimode W states with nonadiabatic error less than 1%. Finally, we propose a superconducting circuit design to catch and release the W states, and shows the experimental feasibility of the multimode multiqubit quantum Rabi model.
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