Low-voltage and extremely flexible electrothermal bimorph actuators were fabricated in a simple, efficient and scalable process. The bimorph actuators were made of flexible silver nanowire (AgNW) based heaters, which exhibited a fast heating rate of 18 °C s and stable heating performance with large bending. The actuators offered the largest bending angle (720°) or curvature (2.6 cm) at a very low actuation voltage (0.2 V sq or 4.5 V) among all types of bimorph actuators that have been reported to date. The actuators can be designed and fabricated in different configurations that can achieve complex patterns and shapes upon actuation. Two applications of this type of soft actuators were demonstrated towards biomimetic robotics - a crawling robot that can walk spontaneously on ratchet surfaces and a soft gripper that is capable of manipulating lightweight and delicate objects.
Several strategies are recently exploited to transform 2D sheets into desired 3D structures. For example, soft materials can be morphed into 3D continuously curved structures by inducing nonhomogeneous strain. On the other hand, rigid materials can be folded, often by origami/ kirigami-inspired approaches (i.e., flat sheets are folded along predesigned crease patterns). Here, for the first time, combining the two strategies, composite sheets are fabricated by embedding rigid origami/ kirigami skeleton with creases into heat shrinkable polymer sheets to create novel 3D structures. Upon heating, shrinkage of the polymer sheets is constrained by the origami/kirigami patterns, giving rise to laterally nonuniform strain. As a result, Gaussian curvature of the composite sheets is changed, and flat sheets are transformed into 3D curved structures. A series of 3D structures are folded using this approach, including cones and truncated pyramids with different base shapes. Flat origami loops are folded into step structures. Tessellation of origami loops is transformed into 3D checkerboard pattern.
Morphing structures are often engineered with stresses introduced into a flat sheet by leveraging structural anisotropy or compositional heterogeneity. Here, we identify a simple and universal diffusion-based mechanism to enable a transient morphing effect in structures with parametric surface grooves, which can be realized with a single material and fabricated using low-cost manufacturing methods (e.g., stamping, molding, and casting). We demonstrate from quantitative experiments and multiphysics simulations that parametric surface grooving can induce temporary asynchronous swelling or deswelling and can transform flat objects into designed, three-dimensional shapes. By tuning the grooving pattern, we can achieve both zero (e.g., helices) and nonzero (e.g., saddles) Gaussian curvature geometries. This mechanism allows us to demonstrate approaches that could improve the efficiency of certain food manufacturing processes and facilitate the sustainable packaging of food, for instance, by creating morphing pasta that can be flat-packed to reduce the air space in the packaging.
FeMoO 4 hollow microspheres were prepared via a template-free hydrothermal method using FeCl 2 and Na 2 MoO 4 as the starting reaction reagents and distilled water as the solvent. The crystal structure, morphology and UV-vis reflection property of the as-synthesized products are characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy and UV-vis diffuse reflectance spectroscopy. The hollow microspheres have diameters ranging from 3 to 5 mm, hollow interiors of y2.5 mm and the shell is constructed by numerous nanoparticles with sizes of 100-200 nm. The effects of reaction temperature, concentration of reaction reagents and reaction times have been studied. The formation mechanism of the FeMoO 4 hollow microspheres is related to the chemical conversion-induced Ostwald ripening process.
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