Yttrium lithium fluoride single crystals doped with trivalent lanthanide ions Pr3+ and Yb3+ are prepared by an improved Bridgman method. X-ray diffraction, photoluminescence excitation, and emission spectra and decay curves are measured to investigate the structural and luminescent properties of the crystals. An efficient near-infrared quantum cutting downconversion from the crystals was observed. The downconversion involves the emission of two near-infrared photons for each blue photon absorbed at 480 nm via cross relaxation energy transfer from Pr3+ to Yb3+. Decay curve fitting using a modified Inokuti-Hirayama expression indicates dipole-dipole energy transfer from Pr3+ to Yb3+, which is consistent with the expected cross-relaxation scheme. The maximum quantum cutting efficiency approaches up to 168.4% in LiYF4: 0.28 mol. % Pr3+ and 6.02 mol. % Yb3+, and this is equivalent to 68.4% energy transfer efficiency.

Deep-red emission with a peak intensity at 712 nm is observed from the Mn4+/Mg2+ co-doped CaGdAlO4 phosphor for plant cultivation.

Multiscale internal/external interfaces are constructed to break the paradox of a high dielectric constant with decreased breakdown strength for superior energy storage capability. An ultrahigh discharged energy density of ∼25.26 J cm−3 is achieved.

Infra-red emission (980 nm) of sub 10 nm Yb3+-doped NaYF4 nanoparticles has been sensitized through the excitation of 2-hydroxyperfluoroanthraquinone chromophore (1,2,3,4,5,6,7-heptafluro-8-hydroxyanthracene-9,10-dione) functionalizing the nanoparticle surface. The sensitization is achieved with a broad range of visible light excitation (400–600 nm). The overall near infra-red (NIR) emission intensity of Yb3+ ions is increased by a factor 300 as a result of the broad and strong absorption of the chromophore compared with ytterbium’s intrinsic absorption. Besides the Yb3+ NIR emission, the hybrid composite shows organic chromophore-based visible emission in the orange-red region of the spectrum. We observe the energy migration process from the sensitized Yb3+ ions at the surface to those in the core of the particle using time-resolved optical spectroscopy. This highlights that the local environments for emitting Yb3+ ions at the surface and center of the nanoparticle are not identical, which causes important differences in the NIR emission dynamics. Based on the understanding of these processes, we suggest a simple strategy to control and modulate the decay time of the functionalized Yb3+-doped nanoparticles over a relatively large range by changing physical or chemical parameters in this model system.

Tb/Yb codoped NaLuF single crystals with near-infrared (NIR) emission are achieved by an improved Bridgman approach. Energy transfer from Tb to Yb ions is affirmed by the photoluminescence (PL) emission spectra and decay curves characterization. On the basis of the analysis of energy transfer rate dependence on the Yb concentration, the interaction between Tb and Yb ions in NaLuF single crystals is confirmed through the one-to-one energy transfer process. Results demonstrate that the prepared NaLuF single crystals might be promising candidates to convert sunlight to improve the performance of the silicon solar cells.

No abstract

These findings suggest teaching/learning strategies and curricular design issues that may lead to greater student and faculty member cultural understandings.

Erbium complexes with a fluorinated organic core shell linked to a hydrogen-containing shell, have been synthesized using the click reaction between erbium(iii) bis(perfluoro-4-azidophenyl)phosphinate and a series of alkynes.