Sensors based on conductive hydrogels have received extensive attention in various fields, such as artificial intelligence, electronic skin, and health monitoring. However, the poor resilience and fatigue resistance, icing, and water loss of traditional hydrogels greatly limit their application. Herein, an ionic conductive organohydrogel (PAC-Zn) was prepared for the first time by copolymerization of cardanol and acrylic acid in water/1,3butanediol as a binary solvent system. A very small amount of cardanol (1% cardanol of total monomers) could not only significantly improve the tensile strength (∼4 times) and toughness (∼3 times) of PAA but also improve its extensibility. Due to the presence of 1,3-butanediol, PAC-Zn showed outstanding tolerance for freezing (−45 °C) and drying (over 85% moisture retention after 15 days of storage in a 37 °C oven). Compared with ethylene glycol and glycerol as antifreeze agents used in organohydrogels, the addition of 1,3-butanediol endowed the organohydrogel with not only similar frost resistance but also better mechanical performance. Besides, PAC-Zn exhibited fast resilience (almost no hysteresis loop) and excellent antifatigue ability. More importantly, a PAC-Zn organohydrogel-based sensor could detect human motion in real time (wrist, elbow, finger, and knee joints), revealing its fast response, good sensitivity, and stable electromechanical repeatability. In conclusion, the multifunctional PAC-Zn organohydrogel is expected to become a potential and promising candidate in the field of strain sensors under a broad range of environmental temperatures.
The syntheses of new macrocyclic molecules containing calixarene and discotic triphenylene units in good yields are reported. Structural and conformational characterization of these new compounds was achieved by UV/Vis, FTIR, and NMR spectroscopy; mass spectrometry; and elemental analysis. The liquid‐crystalline behavior was studied by polarizing optical microscopy, differential scanning calorimetry, and X‐ray diffraction. The symmetrical calix[4]arene‐linked triphenylene dimer with a C10 chain (2b) exhibited the liquid‐crystalline behavior of a calixarene bowlic column with two triphenylene units as ancillary lateral columns.
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