a-plane GaN templates and coalesced epitaxial lateral overgrown (ELOG) films on r-plane sapphire substrates were investigated by x-ray diffraction (XRD). The a-plane GaN templates were found to have [0001]-oriented stripe-features, which is related to anisotropic mosaicity. For the mosaic blocks, the mosaicity reached the largest and the smallest values along the [11̄00] and the [0001] directions. The ELOG procedure with the SiO2 mask stripes perpendicular to the [0001] direction limits the preferable growth along this direction, and thereby enhances the [11̄00] growth. This leads to large-area, featureless, a-plane GaN films for which the wing tilt and not the fine mosaic block size becomes the major XRD line-broadening mechanism.
Developing low-temperature deNOx catalysts with high catalytic activity, SO2-tolerance and stability is highly desirable but remains challenging. Herein, by coating the mesoporous TiO2 layers on carbon nanotubes (CNTs)-supported MnOx and CeOx nanoparticles (NPs), we obtained a core-shell structural deNOx catalyst with high catalytic activity, good SO2-tolerance and enhanced stability. Transmission electron microscopy, X-ray diffraction, N2 sorption, X-ray photoelectron spectroscopy, H2 temperature-programmed reduction and NH3 temperature-programmed desorption have been used to elucidate the structure and surface properties of the obtained catalysts. Both the specific surface area and chemisorbed oxygen species are enhanced by the coating of meso-TiO2 sheaths. The meso-TiO2 sheaths not only enhance the acid strength but also raise acid amounts. Moreover, there is a strong interaction among the manganese oxide, cerium oxide and meso-TiO2 sheaths. Based on these favorable properties, the meso-TiO2 coated catalyst exhibits a higher activity and more extensive operating-temperature window, compared to the uncoated catalyst. In addition, the meso-TiO2 sheaths can serve as an effective barrier to prevent the aggregation of metal oxide NPs during stability testing. As a result, the meso-TiO2 overcoated catalyst exhibits a much better stability than the uncoated one. More importantly, the meso-TiO2 sheaths can not only prevent the generation of ammonium sulfate species from blocking the active sites but also inhibit the formation of manganese sulfate, resulting in a higher SO2-tolerance. These results indicate that the design of a core-shell structure is effective to promote the performance of deNOx catalysts.
28Agricultural origins and dispersals are subjects of fundamental importance to archaeology as 29 well as many other scholarly disciplines. These investigations are world-wide in scope and 30 require significant amounts of paleobotanical data attesting to the exploitation of wild 31 progenitors of crop plants and subsequent domestication and spread. Accordingly, for the past 32 few decades the development of methods for identifying the remains of wild and domesticated 33 plant species has been a focus of paleo-ethnobotany. Phytolith analysis has increasingly taken its 34 place as an important independent contributor of data in all areas of the globe, and the volume of 35 literature on the subject is now both very substantial and disseminated in a range of international 36 journals. In this paper, experts who have carried out the hands-on work review the utility and 37 importance of phytolith analysis in documenting the domestication and dispersals of crop plants 38 around the world. It will serve as an important resource both to paleo-ethnobotanists and other 39 scholars interested in the development and spread of agriculture. 40
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