White organic light-emitting devices (WOLEDs) have drawn intense attention in both scientific and industrial communities due to their potential applications in full-color flatpanel displays, back-lighting sources for liquid-crystal displays and solid-state lighting sources. [1,2] To achieve white emission, mixtures of the three red, green and blue (RGB) primary colors or two complementary colors, are typically required. Various approaches towards realizing WOLEDs have been reported, including multilayer structures capable of sequential energy transfer, [3][4][5] multiple component emissive layers containing an appropriate ratio of RGB phosphorescent or fluorescent dopants, [6][7][8][9][10][11][12][13][14] polymer blends containing RGB emitting species, [8][9][10][11][12][13][14][15][16] charge transfer exciplexes or excimers broad emission [4,17] and single component layers that utilize a polymer with broad emission. [18][19][20][21] Polymer light-emitting devices (PLEDs) [8][9][10][11][12][13][14][15] offer the advantages of solution processing, including screen printing and ink-jet deposition, large area coverage, and low power consumption. However, white emission PLEDs are less efficient with respect to power efficiency (PE) and luminous efficiency (LE), when compared with devices fabricated using vacuumdeposition technologies. For example, vacuum deposited WOLEDs have efficiencies that exceed that of the incandescent light bulb (12-17 lm W -1). [1] In contrast, to the best of our knowledge, the most efficient white emission PLEDs are below 10 lm W -1 , [12][13][14] still far away from practical applications for solid-state lighting.In this communication, we report single layer white PLEDs with an emission layer containing a blend of two or three phosphorescent iridium complexes [22] within a poly(N-vinylcarbazole) (PVK)/1,3-bis[(4-tert-butylphenyl)-1,3,4-oxadiazolyl] phenylene (OXD-7) host matrix. Despite their simple architectures and straightforward fabrication procedures, these devices show excellent color purity and considerably improved power efficiencies and luminous efficiencies, when compared to other polymer-based white emission devices. Ideal white light emission occurs near the equi-energy white point with Commission Internationale de L'Eclairage (CIE) coordinate of (0.333, 0.333). In a blend, the contributions from independent emitters need to be carefully balanced so that their collective integrated emission approaches this coordinate. We relied on the previously reported iridium bis(2-(4,6-difluorophenyl)-pyridinato-N,C 2′ ) picolinate (FIrpic, blue emission), iridium tris(2-(4-tolyl)pyridinato-N,C 2′ ) (Ir(mppy) 3 , green emission), and iridium bis(1-phenylisoquinoline) (acetylacetonate) (Ir(piq), red emission); see Figure 1 for molecular structures. PVK was chosen as a host material due to its higher-lying triplet states (3.0 eV), excellent film-forming properties, high glass transition temperature (T g ) (∼ 160°C) and hole transport characteristics.[23] OXD-7 was included into the host matrix...