Luminescence thermometry usually suffer from cellular complexity of the biochemical environment (such as pH and ionic strength), and thus the accuracy and reliability of the determined intracellular temperature are directly affected. Herein, a photoluminescent nanothermometer composed of polymer encapsulated quantum dots (P-QD) has been developed. And the prepared nanothermometer exhibits some advantages: such as non-sensitivity to pH and ionic strength, as well as high detection sensitivity and ultrahigh reversibility. The intracellular temperature was accurately determined under physiological conditions with different pH and ionic strength, and direct measurement of thermogenesis in individual cells has been achieved.
Fire is a typical disaster in the processing industry. Ionic liquids, as a type of green flame retardant, play an important role in process safety. In order to grasp the current research status, hotspots, and frontiers in the field of ionic liquids in flame retardancy, the bibliometric mapping method is applied to study the relevant literature in Web of Science datasets from 2000–2022 in this paper. The results show that the research on ionic liquids in flame retardancy is multidisciplinary and involves some disciplines such as energy science, material science, and environmental protection. Journal of Power Sources, Polymer Degradation and Stability, ACS Applied Materials and Interfaces, and Chemical Engineering Journal are the core journals in the field. The results of keyword co-occurrence indicate that the hotspots of research can be divided into five components: the improvement and application of pure ionic liquids electrolytes, the research of gel polymer electrolytes, applying ionic liquids to enhance the polymer materials’ flame retardancy properties, utilizing ionic liquids and inorganic materials to synergize flame retardant polymers, and using ionic liquids flame retardant to improve material’s multiple properties. The burst terms and time zone diagram’s results point out the combination of computational quantum chemistry to study the flame retardancy mechanism of ionic liquids, the study of fluorinated electrolytes, ionic liquids for smoke suppression, phosphorus-containing ionic liquids for flame retardant, and machine learning-assisted design of ILs flame retardants are the research frontiers and future research trends.
Risk assessment is of great significance in industrial production and sustainable development. Great potential is attributed to machine learning in industrial risk assessment as a promising technology in the fields of computer science and the internet. To better understand the role of machine learning in this field and to investigate the current research status, we selected 3116 papers from the SCIE and SSCI databases of the WOS retrieval platform between 1991 and 2022 as our data sample. The VOSviewer, Bibliometrix R, and CiteSpace software were used to perform co-occurrence analysis, clustering analysis, and dual-map overlay analysis of keywords. The results indicate that the development trend of machine learning in industrial risk assessment can be divided into three stages: initial exploration, stable development, and high-speed development. Machine learning algorithm design, applications in biomedicine, risk monitoring in construction and machinery, and environmental protection are the knowledge base of this study. There are three research hotspots in the application of machine learning to industrial risk assessment: the study of machine learning algorithms, the risk assessment of machine learning in the Industry 4.0 system, and the application of machine learning in autonomous driving. At present, the basic theories and structural systems related to this research have been established, and there are numerous research directions and extensive frontier branches. “Random Forest”, “Industry 4.0”, “supply chain risk assessment”, and “Internet of Things” are at the forefront of the research.
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