Recognizing the pollution characteristics and potential risks of trace metals in sediments are important to protect water ecosystem safety. In the present study, a systematic investigation was performed to assess the pollution and risk level of trace metals in river sediments located in the greatest gold production base in China. The geo-accumulation index was used to assess the contamination degree. The sediment quality guidelines and potential ecological risk index were employed to complete an ecological risk assessment. A noncarcinogenic health risk assessment was also carried out to evaluate potential adverse health risks. Correlations and principal component analyses were applied to check relationships among trace metals and ascertain potential pollution sources. The results suggested that the sediments in the river were most polluted by As, Cd, and Hg followed by Cu, Pb, and Zn. The assessment of potential human health risk revealed that there was no significant non-carcinogenic risk to the inhabitants. Gold mining and smelting activities and the long-term excessive application of fertilizers and agrochemicals were identified as the main anthropogenic releases. This study contributed an understanding that possible sources, contamination degree, and ecological risk level of trace metals in riverine surface sediments in a gold mining area.

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Efficient identification of groundwater contamination is a major issue in the context of groundwater use and protection. This study used a new approach of multi-hydrochemical indicators, including the Cl-Br mass ratio, the hydrochemical facies, and the concentrations of nitrate, phosphate, organic contaminants, and Pb in groundwater to identify groundwater contamination in the Pearl River Delta (PRD) where there is large scale urbanization. In addition, the main factors resulting in groundwater contamination in the PRD were also discussed by using socioeconomic data and principal component analysis. Approximately 60% of groundwater sites in the PRD were identified to be contaminated according to the above six indicators. Contaminated groundwaters commonly occur in porous and fissured aquifers but rarely in karst aquifers. Groundwater contamination in porous aquifers is positively correlated with the urbanization level. Similarly, in fissured aquifers, the proportions of contaminated groundwater in urbanized and peri-urban areas were approximately two times that in non-urbanized areas. Groundwater contamination in the PRD was mainly attributed to the infiltration of wastewater from township-village enterprises on a regional scale. In addition, livestock waste was also an important source of groundwater contamination in the PRD. Therefore, in the future, the supervision of the wastewater discharge of township-village enterprises and the waste discharge of livestock should be strengthened to protect against groundwater contamination in the PRD.

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