Fibers capable of generating axial contraction are commonly seen in nature and engineering applications. Despite the broad applications of fiber actuators, it is still very challenging to fabricate fiber actuators with combined large actuation strain, fast response speed, and high power density. Here, we report the fabrication of a liquid crystal elastomer (LCE) microfiber actuators using a facile electrospinning technique. Owing to the extremely small size of the LCE microfibers, they can generate large actuation strain (~60 percent) with a fast response speed (<0.2 second) and a high power density (400 watts per kilogram), resulting from the nematic-isotropic phase transition of liquid crystal mesogens. Moreover, no performance degradation is detected in the LCE microfibers after 106 cycles of loading and unloading with the maximum strain of 20 percent at high temperature (90 degree Celsius). The small diameter of the LCE microfiber also results in a self-oscillatory behavior in a steady temperature field. In addition, with a polydopamine coating layer, the actuation of the electrospun LCE microfiber can be precisely and remotely controlled by a near-infrared laser through photothermal effect. Using the electrospun LCE microfiber actuator, we have successfully constructed a microtweezer, a microrobot, and a light-powered microfluidic pump.
Efficient mass transport and selective salt rejection are highly desirable for solar or thermally driven seawater desalination, but its realization is challenging. Here a new liquid supply mechanism is proposed, i.e., ionic pumping effect, using a polyelectrolyte hydrogel foam (PHF), demonstrated with poly(sodium acrylate) [P(SA)] embedded in a microporous carbon foam (CF). The PHF simultaneously possesses high osmotic pressure for liquid transport and a strong salt‐rejection effect. The PHF is able to sustain high flux of ≈24 L per m2 per hour (LMH), comparable to the evaporative flux under 15 suns, and a salt rejection ratio over 80%. Compared to the porous carbon foam without the polyelectrolyte hydrogel, i.e., with only the capillary pumping effect, the PHF yields a 42.4% higher evaporative flux, at ≈1.6 LMH with DI water and ≈1.3 LMH with simulated seawater under one‐sun condition due to the more efficient ionic liquid pumping. More importantly, thanks to the strong salt‐rejection effect, the PHF shows a continuous and stable solar‐driven desalination flux of ≈1.3 LMH under one‐sun over 72 h, which has not been achieved before. The successful demonstration of both efficient ionic pumping and strong salt rejection effects makes the PHF an attractive platform for sustainable solar‐driven desalination.
An overview of the National Oceanic and Atmospheric Administration’s (NOAA) current operational Smoke Forecasting System (SFS) is presented. This system is intended as guidance to air quality forecasters and the public for fine particulate matter (≤2.5 μm) emitted from large wildfires and agricultural burning, which can elevate particulate concentrations to unhealthful levels. The SFS uses National Environmental Satellite, Data, and Information Service (NESDIS) Hazard Mapping System (HMS), which is based on satellite imagery, to establish the locations and extents of the fires. The particulate matter emission rate is computed using the emission processing portion of the U.S. Forest Service’s BlueSky Framework, which includes a fuel-type database, as well as consumption and emissions models. The Hybrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model is used to calculate the transport, dispersion, and deposition of the emitted particulate matter. The model evaluation is carried out by comparing predicted smoke levels with actual smoke detected from satellites by the HMS and the Geostationary Operational Environmental Satellite (GOES) Aerosol/Smoke Product. This overlap is expressed as the figure of merit in space (FMS), the intersection over the union of the observed and calculated smoke plumes. Results are presented for the 2007 fire season (September 2006–November 2007). While the highest FMS scores for individual events approach 60%, average values for the 1 and 5 μg m−3 contours for the analysis period were 8.3% and 11.6%, respectively. FMS scores for the forecast period were lower by about 25% due, in part, to the inability to forecast new fires. The HMS plumes tend to be smaller than the corresponding predictions during the winter months, suggesting that excessive emissions predicted for the smaller fires resulted in an overprediction in the smoke area.
Focusing particles and cells into a tight stream is often required in order for continuous flow detection, counting and sorting. So far a variety of particle focusing methods have been developed in microfluidic devices, among which magnetic focusing is still relatively new. We develop in this work an approach to embedding symmetrically two repulsive permanent magnets about a straight rectangular microchannel in a PDMS-based microfluidic device. The closest distance between the magnets is limited only by the sizes of the embedded and holder magnets involved in the fabrication process. The developed device is used to implement and investigate the three-dimensional magnetic focusing of polystyrene particles in ferrofluid microflow with both the top-and side-view visualizations. The effects of flow speed and particle size on the particle focusing effectiveness are studied. The developed device is also applied to magnetically focus yeast cells in ferrofluid, which proves to be biocompatible as verified by a cell viability test. In addition, an analytical model is developed and found to be able to predict the experimentally observed particle and cell focusing behaviors with reasonable agreement.
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