Near-surface reaction of CO 2 -bearing fluids with silicate minerals in peridotite and basalt forms solid carbonate minerals. Such processes form abundant veins and travertine deposits, particularly in association with tectonically exposed mantle peridotite. This is important in the global carbon cycle, in weathering, and in understanding physical-chemical interaction during retrograde metamorphism. Enhancing the rate of such reactions is a proposed method for geologic CO 2 storage, and perhaps for direct capture of CO 2 from near-surface fluids. We review, synthesize, and extend inferences from a variety of sources. We include data from studies on natural peridotite carbonation processes, carbonation kinetics, feedback between permeability and volume change via reaction-driven cracking, and proposed methods for enhancing the rate of natural mineral carbonation via in situ processes ("at the outcrop") rather than ex situ processes ("at the smokestack"). 545 Annu. Rev. Earth Planet. Sci. 2011.39:545-576. Downloaded from www.annualreviews.org by University of British Columbia on 10/27/12. For personal use only.
An in‐depth Sr‐Nd‐Pb‐He‐Os isotope and trace element study of the EMII‐defining Samoan hot spot lavas leads to a new working hypothesis for the origin of this high 87Sr/86Sr mantle end‐member. Systematics of the Samoan fingerprint include (1) increasing 206Pb/204Pb with time ‐ from 18.6 at the older, western volcanoes to 19.4 at the present‐day hot spot center, Vailulu'u Seamount, (2) en‐echelon arrays in 206Pb/204Pb – 208Pb/204Pb space which correspond to the two topographic lineaments of the 375 km long volcanic chain – this is much like the Kea and Loa Trends in Hawai'i, (3) the highest 87Sr/86Sr (0.7089) of all oceanic basalts, (4) an asymptotic decrease in 3He/4He from 24 RA [Farley et al., 1992] to the MORB value of 8 RA with increasing 87Sr/86Sr, and (5) mixing among four components which are best described as the “enriched mantle”, the depleted FOZO mantle, the (even more depleted) MORB Mantle, and a mild HIMU (high 238U/204Pb) mantle component. A theoretical, “pure” EMII lava composition has been calculated and indicates an extremely smooth trace element pattern of this end‐member mantle reservoir. The standard recycling model (of ocean crust/sediment) fails as an explanation for producing Samoan EM2, due to these smooth spidergrams for EM2 lavas, low 187Os/188Os ratios and high 3He/4He (>8 RA). Instead, the origin of EM2 has been modeled with the ancient formation of metasomatised oceanic lithosphere, followed by storage in the deep mantle and return to the surface in the Samoan plume.
, most models for the creation of the EM1 and EM2 mantle reservoirs invoke a small portion of lithologically distinct sediments that have been recycled into the mantle 9,13 .
Current models of drainage evolution suggest that the non‐dendritic patterns seen in rivers in SE Asia reflect progressive capture of headwaters away from the Red River during and as a result of surface uplift of Eastern Asia. Mass balancing of eroded and deposited rock volumes demonstrates that the Red River catchment must have been much larger in the past. In addition, the Nd isotope composition of sediments from the Hanoi Basin, Vietnam, interpreted as paleo‐Red River sediments, shows rapid change during the Oligocene, before ∼24 Ma. We interpret this change to reflect large‐scale drainage capture away from the Red River, possibly involving loss of the middle Yangtze River. Reorganization was triggered by regional tilting of the region towards the east. This study constrains initial surface uplift in eastern Tibet and southwestern China to be no later than 24 Ma, well before major surface uplift and gorge incision after 13 Ma.
Climate is one of the principal controls setting rates of continental erosion. Here we present the results of a provenance analysis of Holocene sediments from the Indus delta in order to assess climatic controls on erosion over millennial time scales. Bulk sediment Nd isotope analysis reveals a number of changes during the late Pleistocene and early Holocene (at 14-20, 11-12 and 8-9 ka) away from erosion of the Karakoram and toward more sediment fl ux from the Himalaya. Radiometric Ar-Ar dating of muscovite and U-Pb dating of zircon sand grains indicate that the Lesser Himalaya eroded relatively more strongly than the Greater Himalaya as global climate warmed and the summer monsoon intensifi ed after 14 ka. Monsoon rains appear to be the primary force controlling erosion across the western Himalaya, at least over millennial time scales. This variation is preserved with no apparent lag in sediments from the delta, but not in the deep Arabian Sea, due to sediment buffering on the continental shelf.
RESULTSIn contrast to the ~1 ε Nd unit shift seen between modern and glacial sediments in the Bengal Fan (Colin et al., 1999), we use a moving average plot (Fig. 2B) to show that ε Nd changed from ~11 to ~12 between sedi-
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