Graphene oxide samples prepared in various laboratories following a diversity of synthesis protocols based on Brodie's (BGO) and Hummers/Offeman's (HGO) methods were compared in respect of their inplane moduli. A simple wrinkling method allowed for a spatial resolution <1.5 mm by converting the wrinkling frequency. Quite surprisingly, a drastic variation of the in-plane moduli was found spanning the range from 600 GPa for the best BGO types, which is in the region of chemically derived graphene, all the way down to less than 200 GPa for HGO types. This would suggest that there are no two equal GO samples and GO should not be regarded a compound but rather a class of materials with very variable physical properties. While large differences between Brodie's and Hummers/Offeman's types might have been expected, even within the group of Hummers/Offeman's types pronounced differences are observed that, based on 13 C solid-state NMR, were related to over-functionalization versus over-oxidation.
A moulding technique is presented for the simultaneous photostructuring on the μm scale of hydrogels with nanomaterials on one substrate, usable for the fabrication of microfluidic double-chamber reactors.
We introduce a novel concept for
mechanosensitive hydrogel microparticles, which translate deformation
into changes in fluorescence and can thus function as mechanical probes.
The hydrogel particles with controlled polymer network are produced
via droplet microfluidics from poly(ethylene glycol) (PEG) precursors.
Förster resonance energy transfer donors and acceptors are
coupled to the PEG hydrogel network for reporting local deformations
as fluorescence shifts. We show that global network deformations,
which occur upon drying/rehydration, can be detected via a characteristic
fluorescence shift. Combined characterization with confocal laser
scanning microscopy and atomic force microscopy (AFM) shows that also
local deformation of the particles can be detected. Using AFM, the
mechanical properties of the particles can be quantified, which allows
linking strain with stress and thus force sensing in a three-dimensional
environment. Microfluidic material design allows for precisely varying
the size of our hydrogel microparticles as well as their mechanical
properties and polymer network structure with regard to the choice
of the macromolecular precursors and their functionalization with
fluorophores. Thus, concomitant changes in mechanical properties and
mechanosensitivity qualify these hydrogel microparticles as an adjustable
material platform for force sensing in structural mechanics or cell
culturing.
Ordered heterostructures of layered materials where interlayers with different reactivities strictly alternate in stacks offer predetermined slippage planes that provide a precise route for the preparation of bilayer materials. We use this route for the synthesis of a novel type of reinforced layered silicate bilayer that is 15 % stiffer than the corresponding monolayer. Furthermore, we will demonstrate that triggering cleavage of bilayers by osmotic swelling gives access to a generic toolbox for an asymmetrical modification of the two vis-à-vis standing basal planes of monolayers. Only two simple steps applying arbitrary commercial polycations are needed to obtain such Janus-type monolayers. The generic synthesis route will be applicable to many other layered compounds capable of osmotic swelling, rendering this approach interesting for a variety of materials and applications.
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