Three related diagnostics are used to evaluate the representation of chemical transport processes in the extratropical upper troposphere and lower stratosphere (UTLS) by chemistry‐transport and chemistry‐climate models. The diagnostics are based on in situ observations of ozone, carbon monoxide, water vapor profiles (obtained on board the NASA ER‐2 research aircraft, near 65°N and during 1997), and their interrelationships in the UTLS. The first diagnostic compares the observed and modeled UTLS trace gas profiles in a relative altitude coordinate. The second one compares the observed and modeled UTLS tracer relationships. The third one compares the observed and modeled thickness of the tropopause transition layer. Together, they characterize the model's ability to reproduce the observed chemical distribution in the UTLS region and chemical transition across the extratropical tropopause. These are key indicators of whether the contributions of dynamics and chemistry to this region are correctly represented in the models. These diagnostics are used to evaluate the performance of an NCAR chemistry‐transport model (CTM), MOZART‐3, and a chemistry‐climate model (CCM), WACCM3. Results from four model runs with different meteorological fields and grid resolution are examined. Overall, the NCAR models show qualitative agreement with the observations in the location of the chemical transition across the extratropical tropopause. Quantitatively, there are significant differences between the modeled and the observed chemical distributions. Both the meteorological field and grid resolutions are contributing factors to the differences.
[1] During the Stratosphere-Troposphere Analyses of Regional Transport (START) experiment in December 2005, the behavior of the extratropical tropopause was examined under a variety of dynamical conditions. Using in situ measurements of ozone and water vapor, on board the new NSF/NCAR research aircraft Gulfstream V, and data from large-scale meteorological analyses, we address issues of the tropopause definitions and sharpness. Comparisons of the data from two flights show that the sharpness of chemical transitions across the tropopause varies with the sharpness of the static stability change across the tropopause. Using tracer correlations, air masses of mixed stratospheric and tropospheric characteristics are identified. The mixed air mass does not form a uniform mixing layer near the tropopause, but rather shows strong spatial variation. A depth of mixed air ($5 km in vertical distribution) is found on the cyclonic side of the polar jet, where the thermal gradient is weak and significant separation occurs between the thermal and the dynamical tropopause. Away from the jet or on the anticyclonic side of the jet, where the stability gradient is strong, the chemical transition across the tropopause was much more abrupt and shows minimum mixing. In both cases (either significant or minimal mixing), the thermal tropopause is shown to be approximately at the center of the mixing layer, and the altitude relative to the thermal tropopause is found to be an effective coordinate for locating the chemical transition. To further understand the role of the thermal and dynamical tropopause as a chemical transport boundary, tracer correlations are used to examine the chemical characteristics, and the trajectory calculations are used to infer the fate of the air mass between the thermal and dynamic tropopauses in the region of significant separation. The tracer correlation analysis shows that the air mass in this region is a mixture of stratospheric and tropospheric air but predominantly of tropospheric characteristics. Trajectory model calculations show that a significant fraction of the air parcels in this region ended in the mid to lower troposphere, which suggest the irreversible nature of the observed stratospheric intrusion.
[1] Model simulations with the Chemical Lagrangian Model of the Stratosphere (CLaMS) driven by wind fields of the National Center for Environmental Prediction (NCEP) were performed in the midlatitude tropopause region in April 2008 to study two research flights conducted during the START08 campaign. One flight targeted a deep tropospheric intrusion and another flight targeted a deep stratospheric intrusion event, both of them in the vicinity of the subtropical and polar jet. Air masses with strong signatures of mixing between stratospheric and tropospheric air masses were identified from measured CO-O 3 correlations, and the characteristics were reproduced by CLaMS model simulations. CLaMS simulations in turn complement the observations and provide a broader view of the mixed region in physical space. Using artificial tracers of air mass origin within CLaMS yields unique information about the transport pathways and their contribution to the composition in the mixed region from different transport origins. Three different regions are examined to categorize dominant transport processes: (1) on the cyclonic side of the polar jet within tropopause folds where air from the lowermost stratosphere and the cyclonic side of the jet is transported downward into the troposphere, (2) on the anticyclonic side of the polar jet around the 2 PVU surface air masses, where signatures of mixing between the troposphere and lowermost stratosphere were found with large contributions of air masses from low latitudes, and (3) in the lower stratosphere associated with a deep tropospheric intrusion originating in the tropical tropopause layer (TTL). Moreover, the time scale of transport from the TTL into the lowermost stratosphere is in the range of weeks whereas the stratospheric intrusions occur on a time scale of days.
Abstract. Satellite retrievals of methane (CH 4 ) using the Atmospheric Infrared Sounder (AIRS) on the EOS/Aqua platform from 2003-2007 show a strong, plume-like enhancement of CH 4 in the middle to upper troposphere over South Asia during July, August and September, with the maximum occurring in early September. Simulations using the global tracer model version 3 (TM3) also show similar seasonal enhancement of CH 4 in the same region. The model results also suggest that this enhancement is associated with transport processes and local surface emissions, thus the observations of tropospheric CH 4 during the monsoon season may be used to constrain the models for a better estimation of Asian CH 4 sources. Further comparisons between the AIRS retrievals and the model simulations suggest a possible overestimate of emissions from rice paddies in Southeast Asia in the scenario with the global emissions from rice of 60 Tg yr −1 . Moreover, the observed tropospheric CH 4 enhancement from AIRS provides evidence for the strong transport of atmospheric pollutants from the lower to the upper troposphere in Asia during the monsoon season. The observed rapid disappearance of the local CH 4 maximum in September may provide valuable information for studying the dissipation of the Tibetan anticyclone and the withdrawal of monsoon.
[1] We evaluate ozone profile retrievals from the Atmospheric Infrared Sounder (AIRS), the Infrared Atmospheric Sounding Interferometer (IASI), and the Ozone Monitoring Instrument (OMI) using in situ measurements collected on board the NSF/NCAR Gulfstream-V aircraft during the Stratosphere-Troposphere Analyses of Regional Transport 2008 (START08) experiment. The focus of this study is to examine how well the satellite retrieval products capture the ozone gradients and variability in the extratropical upper troposphere lower stratosphere (UTLS). The AIRS retrieval examined is version 5, while IASI and OMI retrievals are research products. All satellite instruments show excellent ability in capturing synoptic-scale ozone gradients associated with strong potential vorticity (PV) gradients. The positive ozone-PV correlation near the tropopause is also well represented in the satellite data in comparison to collocated aircraft measurements. During aircraft cruise legs, more than 90% of collocated satellite retrievals agree with aircraft measurements within ±50% for ozone mixing ratios greater than 200 ppbv. Below 200 ppbv, AIRS and IASI retrievals show significant positive biases, while OMI shows both positive and negative biases. Ozone gradients across the tropopause are well-captured, with median values within 30% (positive for AIRS and IASI, negative for OMI) and variances within ±50%. Ozone variability in the UTLS is captured by the satellite retrievals at the 80% level. In the presence of high clouds, however, the infrared retrievals show the largest positive biases. Despite the limited vertical information content, the high horizontal coverage and long-term data availability make these satellite data sets a valuable asset for UTLS research.
Motivated by the need of obtaining a more accurate global ozone distribution in the upper troposphere and lower stratosphere (UTLS), we have investigated the use of a tropopause-based (TB) ozone climatology in ozone profile retrieval from the Ozone Monitoring Instrument (OMI). Due to the limited vertical ozone information in the UTLS region from OMI backscattered ultraviolet radiances, better climatological a priori information is important for improving ozone profile retrievals. We present the new TB climatology and evaluate the result of retrievals against previous work. The TB climatology is created using ozonesonde profiles from 1983 through 2008 extended with climatological ozone data above sonde burst altitude (~35 km) with the corresponding temperature profiles used to identify the thermal tropopause. The TB climatology consists of the mean states and 1σ standard deviations for every month for each 10° latitude band. Compared to the previous TB climatology by Wei et al. (2010), three additional processes are applied in deriving our climatology: (1) using a variable shifting offset to define the TB coordinate, (2) separating ozonesonde profiles into tropical and extratropical regimes based on a threshold of 14 km in the thermal tropopause height, and (3) merging with an existing climatology from 5–10 km above the tropopause. The first process changes the reference of profiles to a variable position between local and mean tropopause heights within ±5 km of the tropopause and to the mean tropopause elsewhere. The second helps to preserve characteristics of either tropical or extratropical ozone structures depending on tropopause height, especially in the subtropical region. The third improves the climatology above ozonesonde burst altitudes and in the stratosphere by using climatology derived from many more satellite observations of ozone profiles. With aid from the National Centers for Environmental Prediction (NCEP) Global Forecast System (GFS) tropopause height, the new climatology and retrieval can better represent the dynamical variability of ozone in the tropopause region. The new retrieval result demonstrates significant improvement of UTLS ozone, especially in the extratropical UTLS, when evaluated using ozonesonde measurements and the meteorological data. The use of TB climatology significantly enhances the spatial consistency and the statistical relationship between ozone and potential vorticity/tropopause height in the extratropical UTLS region. Comparisons with ozonesonde measurements show substantial improvements in both mean biases and their standard deviations over the extratropical lowermost stratosphere and upper troposphere. Overall, OMI retrievals with the TB climatology show improved ability in capturing ozone gradients across the tropopause found in tropical/extratropical ozonesonde measurements
This paper gives an overview of a unique set of ship-based atmospheric data acquired over the tropical Atlantic Ocean during boreal spring and summer as part of ongoing National Oceanic and Atmospheric Administration (NOAA) Aerosols and Ocean Science Expedition (AEROSE) field campaigns. Following the original 2004 campaign onboard the Ronald H. Brown, AEROSE has operated on a yearly basis since 2006 in collaboration with the NOAA Prediction and Research Moored Array in the Tropical Atlantic (PIRATA) Northeast Extension (PNE). In this work, attention is given to atmospheric soundings of ozone, temperature, water vapor, pressure, and wind obtained from ozonesondes and radiosondes launched to coincide with low earth orbit environmental satellite overpasses [MetOp and the National Aeronautics and Space Administration (NASA) A-Train]. Data from the PNE/ AEROSE campaigns are unique in their range of marine meteorological phenomena germane to the satellite missions in question, including dust and smoke outflows from Africa, the Saharan air layer (SAL), and the distribution of tropical water vapor and tropical Atlantic ozone. The multiyear PNE/AEROSE sounding data are valuable as correlative data for prelaunch phase validation of the planned Joint Polar Satellite System (JPSS) and NOAA Geosynchronous Operational Environmental Satellite R series (GOES-R) systems, as well as numerous other science applications. A brief summary of these data, along with an overview of some important science highlights, including meteorological phenomena of general interest, is presented.
IntroductionWater vapor is an important constituent of the atmosphere. The vertical distribution of moisture is important in determining atmospheric stability. Water vapor is also the most radiatively active atmospheric trace gas in the infrared (Ramanathan 1988) and thus could produce strong forcing from feedback associated with anthropogenically driven climate change (Cess 1990). In addition, there is significant variability in the distribution of water vapor on temporal and spatial scales smaller than is currently being measured by the standard techniques Howard University Raman Lidar
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