This research investigates the level and degradation of oil at ten selected Gulf saltmarsh sites months after the 2010 BP Macondo-1 well oil spill. Very high levels (10-28%) of organic carbon within the heavily oiled sediments are clearly distinguished from those in pristine sediments (<3%). Dissolved organic carbon in contaminated pore-waters, ranging up to hundreds of mg/kg, are 1 to 2 orders of magnitude higher than those at pristine sites. Heavily oiled sediments are characterized by very high sulfide concentrations (up to 80 mg/kg) and abundance of sulfate reducing bacteria. Geochemical biomarkers and stable carbon isotope analyses fingerprint the presence of oils in sediments. Ratios of selected parameters calculated from the gas chromatograph spectra are in a remarkable narrow range among spilled oils and initial BP crude. At oiled sites dominated by C(4) plants, δ(13)C values of sediments (-20.8 ± 2.0‰) have been shifted significantly lower compared to marsh plants (-14.8 ± 0.6‰) due to the inflow of isotopically lighter oil (-27 ± 0.2‰). Our results show that (1) lighter compounds of oil are quickly degraded by microbes while the heavier fractions of oil still remain and (2) higher inputs of organic matter from the oil spill enhance the key microbial processes associated with sulfate reducing bacteria.
Assessing the impacts of climate changes on water quality requires an understanding of the biogeochemical cycling of trace metals. Evidence from research on alluvial aquifers and coastal watersheds shows direct impacts of climate change on the fate and transformation of trace metals in natural environments. The case studies presented here use field data and numerical modeling techniques to test assumptions about the effects of climate change on natural arsenic contamination of groundwater in alluvial aquifers and mercury bioaccumulation in coastal salt marshes. The results show that the rises of sea level and river base during the warm Holocene period has led to an overall increase in groundwater arsenic concentration due to the development of reducing geochemical
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