Electromechanical coupling in electroactive polymers (EAPs) has been widely applied for actuation and is also being increasingly investigated for sensing chemical and mechanical stimuli. EAPs are a unique class of materials, with low-moduli high-strain capabilities and the ability to conform to surfaces of different shapes. These features make them attractive for applications such as wearable sensors and interfacing with soft tissues. Here, we review the major types of EAPs and their sensing mechanisms. These are divided into two classes depending on the main type of charge carrier: ionic EAPs (such as conducting polymers and ionic polymer–metal composites) and electronic EAPs (such as dielectric elastomers, liquid-crystal polymers and piezoelectric polymers). This review is intended to serve as an introduction to the mechanisms of these materials and as a first step in material selection for both researchers and designers of flexible/bendable devices, biocompatible sensors or even robotic tactile sensing units.
This literature review covers the solubility and processability of fluoropolymer polyvinylidine fluoride (PVDF). Fluoropolymers consist of a carbon backbone chain with multiple connected C–F bonds; they are typically nonreactive and nontoxic and have good thermal stability. Their processing, recycling and reuse are rapidly becoming more important to the circular economy as fluoropolymers find widespread application in diverse sectors including construction, automotive engineering and electronics. The partially fluorinated polymer PVDF is in strong demand in all of these areas; in addition to its desirable inertness, which is typical of most fluoropolymers, it also has a high dielectric constant and can be ferroelectric in some of its crystal phases. However, processing and reusing PVDF is a challenging task, and this is partly due to its limited solubility. This review begins with a discussion on the useful properties and applications of PVDF, followed by a discussion on the known solvents and diluents of PVDF and how it can be formed into membranes. Finally, we explore the limitations of PVDF’s chemical and thermal stability, with a discussion on conditions under which it can degrade. Our aim is to provide a condensed overview that will be of use to both chemists and engineers who need to work with PVDF.
This paper reports an opto-actuable device fabricated using micro-machined silicon moulds. The actuating component of the device is made from a composite material containing carbon nanotubes (CNTs) embedded in a liquid crystal elastomer (LCE) matrix. We demonstrate the fabrication of a patterned LCE-CNT film by a combination of mechanical stretching and thermal cross-linking. The resulting poly-domain LCE-CNT film contains 'blister-shaped' mono-domain regions, which reversibly change their shape under light irradiation and hence can be used as dynamic Braille dots. We demonstrate that blisters with diameters of 1.0 and 1.5 mm, and wall thickness 300 μm, will mechanically contract under irradiation by a laser diode with optical power up to 60 mW. The magnitude of this contraction was up to 40 μm, which is more than 10% of their height in the 'rest' state. The stabilization time of the material is less than 6 s for both actuation and recovery. We also carried out preliminary tests on the repeatability of this photo-actuation process, observing no material or performance degradation. This manufacturing approach establishes a starting point for the design and fabrication of wide-area tactile actuators, which are promising candidates for the development of new Braille reading applications for the visually impaired.
Liquid crystalline elastomers (LCEs) exhibit a number of remarkable physical effects, including a uniquely high-stroke reversible mechanical actuation triggered by external stimuli. Fundamentally, all such stimuli affect the degree of liquid crystalline order in the polymer chains cross-linked into an elastic network. Heat and the resulting thermal actuation act by promoting entropic disorder, as does the addition of solvents. Photo-isomerization is another mechanism of actuation, reducing the orientational order by diminishing the fraction of active rod-like mesogenic units, mostly studied for azobenzene derivatives incorporated into the LCE composition. Embedding nanoparticles provides a new, promising strategy to add functionality to LCEs and ultimately enhance their performance as sensors and actuators. The motivation for the combination of nanoparticles with LCEs is to provide better-controlled actuation stimuli, such as electric and magnetic fields, and broad-spectrum light, by selecting and configuring the appropriate nanoparticles in the LCE matrix. Here we give an overview of recent advances in this area with a focus on preparation, physical properties and actuation performance of the resultant nanocomposites.
Monodomain liquid crystal elastomers (LCEs) are new materials uniquely suitable for artificial muscles, as they undergo large reversible uniaxial shape changes, with strains of 20-500% and stresses of 10-100 kPa, falling exactly into the dynamic range of a muscle. LCEs exhibit little to no fatigue over thousands of actuation cycles. Their practical use has been limited, however, owing to the difficulty of synthesizing components, achieving consistent alignment during cross-linking across the whole material and often a high nematic-isotropic phase transition temperature. The most widely studied method for LC alignment involves mechanical stretching of the material during one of two cross-linking steps, which makes fabrication difficult to control and lends itself mainly to samples that can be easily grasped (with sizes of the order of mm). In this article, we describe a method of adapting the LCE synthesis to microscale objects, achieving monodomain alignment with a single cross-linking step, and lowering the cycling temperature. LCE precursor droplets are embedded in and then stretched in a polymer matrix at high temperature. Confinement of the uniaxially stretched droplets maintains the alignment achieved during stretching and allows us to eliminate one of the cross-linking steps and the variability associated with it. Adding a comonomer during the polymerization leads to lowering of the nematic-to-isotropic transition temperature (58 °C), significantly expanding the range of potential applications for these micromuscles. We demonstrate reversible thermal switching of the micromuscles in line with the largest strain changes observed for side-chain LCEs and a differential scanning calorimetry characterization of the material phase transitions. The method demonstrates the parallel fabrication of many microscale actuators and is amenable to further scale-up and manufacturing.
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