Bulk Cs 3 Bi 2 I 9 exhibits zero-dimensional (0-D) perovskite crystal structure at the molecular level, providing scopes for novel optical properties compared to three-dimensional perovskite structures. Here, 0-D refers to the crystal structure irrespective of the size of the crystal. We have prepared colloidal Cs 3 Bi 2 I 9 nanocrystals and elucidated the unique optical properties arising from their 0-D crystal structure. Absorption spectrum at 10 K confirms that the electronic band gap of Cs 3 Bi 2 I 9 nanocrystals is at 2.86 eV, along with a sharp excitonic peak at 2.56 eV, resulting in a very high excitonic binding energy, E b X = 300 meV. Interestingly, we observe two peaks in the photoluminescence spectra at room temperature on both sides of the excitonic absorption energy. Because E b X (300 meV) ≫ effective phonon energy (36 meV), the phonon-mediated relaxation of carriers from conduction band minimum to the excitonic state is suppressed to an extent. Consequently, two photoluminescence peaks related to both the bulk band edge and the excitonic transitions are observed. Furthermore, Rb 3 Bi 2 I 9 nanocrystals have also been synthesized, but they exhibit two-dimensional layered structure, unlike the 0-D structure of Cs 3 Bi 2 I 9 .

The review addresses new advances in metal, bimetallic, metal oxide, and composite particles in their nanoregime for facet-selective catalytic applications. The synthesis and growth mechanisms of the particles have been summarized in brief in this review with a view to develop critical examination of the faceted morphology of the particles for catalysis. The size, shape and composition of the particles have been found to be largely irrelevant in comparison to the nature of facets in catalysis. Thus selective high- and low-index facets have been found to selectively promote adsorption, which eventually leads to an effective catalytic reaction. As a consequence, a high density of atoms rest at the corners, steps, stages, kinks etc on the catalyst surface in order to host the adsorbate efficiently and catalyze the reaction. Again, surface atomic arrangement and bond length have been found to play a dominant role in adsorption, leading to effective catalysis.

A mild, template free protocol has been demonstrated for SnS2 nanoflake formation at the gram level from SnCl2 and thioacetamide (TAA). The SnS2 nanoflakes congregate to nanoflowers and nanoyarns with variable TAA concentrations. BET measurements reveal that the synthesized nanomaterials are highly porous having very high surface area, and the nanoflower has higher surface area than the nanoyarn. The synthesized nanomaterial finds application for promoting photoreduction of extremely toxic and lethal Cr(VI) under visible light irradiation due to their porous nature. The nanoflowers photocatalyst is proved to be superior to nanoyarn due to the increased surface area and higher pore volume. It was also inferred that increased pH decreased the reaction rate. The present result suggests that the morphology-dependent photoreduction of Cr(VI) by SnS2 nanomaterial under visible light exposure will endorse a new technique for harvesting energy and purification of wastewater.

Superhydrophobic surfaces prevent percolation of water droplets and thus render roll-off, self-cleaning, corrosion protection, etc., which find day-to-day and industrial applications. In this work, we developed a facile, cost-effective, and free-standing method for direct fabrication of copper nanoparticles to engender superhydrophobicity for various flat and irregular surfaces such as glass, transparency sheet (plastic), cotton wool, textile, and silicon substrates. The fabrication of as-prepared superhydrophobic surfaces was accomplished using a simple chemical reduction of copper acetate by hydrazine hydrate at room temperature. The surface morphological studies demonstrate that the as-prepared surfaces are rough and display superhydrophobic character on wetting due to generation of air pockets (The Cassie-Baxter state). Because of the low adhesion of water droplets on the as-prepared surfaces, the surfaces exhibited not only high water contact angle (164 ± 2°, 5 μL droplets) but also superb roll-off and self-cleaning properties. Superhydrophobic copper nanoparticle coated glass surface uniquely withstands water (10 min), mild alkali (5 min in saturated aqueous NaHCO3 of pH ≈ 9), acids (10 s in dilute HNO3, H2SO4 of pH ≈ 5) and thiol (10 s in neat 1-octanethiol) at room temperature (25-35 °C). Again as-prepared surface (cotton wool) was also found to be very effective for water-kerosene separation due to its superhydrophobic and oleophilic character. Additionally, the superhydrophobic copper nanoparticle (deposited on glass surface) was found to exhibit antibacterial activity against both Gram-negative and Gram-positive bacteria.