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Zn(O,S) buffer layer electronic configuration is determined by its composition and thickness, tunable through atomic layer deposition. The Zn K and L-edges in the X-ray absorption near edge structure verify ionicity and covalency changes with S content. A high intensity shoulder in the Zn K-edge indicates strong Zn 4s hybridized states and a preferred c-axis orientation. 2–3 nm thick films with low S content show a subdued shoulder showing less contribution from Zn 4s hybridization. A lower energy shift with film thickness suggests a decreasing bandgap. Further, ZnSO4 forms at substrate interfaces, which may be detrimental for device performance.

The new emerging Wire and Arc Additive Manufacturing (WAAM) technology has significant potential to improve material design and efficiency for structural components as well as reducing manufacturing costs. Due to repeated and periodic melting, solidification and reheating of the layers, the WAAM deposition technique results in some elastic, plastic and viscous deformations that can affect material degradation and crack propagation behaviour in additively manufactured components. Therefore, it is crucial to characterise the cracking behaviour in WAAM built components for structural design and integrity assessment purposes. In this work, fatigue crack growth tests have been conducted on compact tension specimens extracted from ER70S-6 steel WAAM built components. The crack propagation behaviour of the specimens extracted with different orientations (i.e. horizontal and vertical with respect to the deposition direction) has been characterised under two different cyclic load levels. The obtained fatigue crack growth rate data have been correlated with the linear elastic fracture mechanics parameter $$\varDelta K$$ Δ K and the results are compared with the literature data available for corresponding wrought structural steels and the recommended fatigue crack growth trends in the BS7910 standard. The obtained results have been found to fall below the recommended trends in the BS7910 standard and above the data points obtained from S355 wrought material. The obtained fatigue growth trends and Paris law constants from this study contribute to the overall understanding of the design requirements for the new optimised functionally graded structures fabricated using the WAAM technique.

The knowledge of self‐healing was developed to ensure more durable and reliable engineering materials. Healing agent encapsulation has shown to be one of the most promising approaches in self‐healing technology. The healing agents were encapsulated within micro/nanocapsules, micro/nanofibers, and vascular‐based networks. Among the methods, using core‐shell nanofibers showed a compromising potential for the development of self‐healing nanofibers with the minimum drawbacks and limitations. The aim of the present paper is to report the recent contributions on the recent progress of self‐healing materials using core‐shell nanofibers to provide insights for the further development of self‐healing polymeric materials both in academic research and scalable fabrication of polymeric parts in the industries.