The
efficiency of organo-lead halide perovskite-based optoelectronic
devices is dramatically lower for amorphous materials compared to
highly crystalline ones. Therefore, it is challenging to optimize
and scale up the production of large-sized single crystals of perovskite
materials. Here, we describe a novel and original approach to preparing
lead halide perovskite single crystals by applying microwave radiation
during the crystallization. The microwave radiation primarily causes
precise heating control in the whole volume and avoids temperature
fluctuations. Moreover, this facile microwave-assisted method of preparation
is highly reproducible and fully automated, it and can be applied
for various different perovskite structures. In addition, this cost-effective
method is expected to be easily scalable because of its versatility
and low energy consumption. The crystallization process has low heat
losses; therefore, only a low microwave reactor power of 8–15
W during the temperature changes and of less than 1 W during the temperature
holding is needed.
This work reports on an optimized procedure to synthesize methylammonium bromide perovskite nanoparticles. The ligand-assisted precipitation synthetic pathway for preparing nanoparticles is a cost-effective and promising method due to its ease of scalability, affordable equipment requirements and convenient operational temperatures. Nevertheless, there are several parameters that influence the resulting optical properties of the final nanomaterials. Here, the influence of the choice of solvent system, capping agents, temperature during precipitation and ratios of precursor chemicals is described, among other factors. Moreover, the colloidal stability and stability of the precursor solution is studied. All of the above-mentioned parameters were observed to strongly affect the resulting optical properties of the colloidal solutions. Various solvents, dispersion media, and selection of capping agents affected the formation of the perovskite structure, and thus qualitative and quantitative optimization of the synthetic procedure conditions resulted in nanoparticles of different dimensions and optical properties. The emission maxima of the nanoparticles were in the 508–519 nm range due to quantum confinement, as confirmed by transmission electron microscopy. This detailed study allows the selection of the best optimal conditions when using the ligand-assisted precipitation method as a powerful tool to fine-tune nanostructured perovskite features targeted for specific applications.
Despite the current advancements, yet improving the intrinsic structure and external environmental stability of hybrid metal halide perovskite nanomaterials is required for developing efficient perovskite-based devices. Up-to-date, a very attractive method is growing and/or embedding perovskite nanocrystals within organic polymeric matrices, or into porous inorganic and hybrid nano/micromaterials (e. g., metal-organic frameworks, mesoporous silica, zeolites, and others), favored through confinement effect within the pores.In this review, we highlighted the last two years of research progress on enhancing the stabilization of perovskite nanoparticles based on methylammonium cations. In the future generation of optoelectronic and photovoltaic devices along with other interesting applied fields, it is predicted that an effective way to trigger the widespread use of this type of perovskite nanocrystals may involve combining different functional host materials, acting as a smarter protection method for the guest nanocrystals.
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