Abstract. The diffraction results for the formation of ice in 86Å diameter pores of a SBA-15 silica sample are analysed to provide information on the characteristics of the ice created in the pores. The asymmetric triplet at ∼1.7Å −1 , which involves several overlapping peaks, is particularly relevant to the different ice phases and contains a number of components that can be individually identified. The use of a set of three peaks with an asymmetric profile to represent the possibility of facetted growth in the pores was found to give an unsatisfactory fit to the data. The alternative method involving the introduction of additional peaks with a normal symmetric profile was found to give excellent fits with five components and was the preferred analytic procedure. Three peaks could be directly linked to the positions for the triplet of hexagonal ice, I h , and one of the other two broad peaks could be associated with a form of amorphous ice. The variation of the peak intensity [and position] was systematic with temperature for both cooling and heating runs. The results indicate that a disordered state of ice is formed as a component with the defective crystalline ices. The position of a broad diffraction peak is intermediate between that of high density [hda] and low-density [lda] amorphous ice. The remaining component peak is less broad but does not relate directly to any of the known ice phases and cannot be assigned to any specific structural feature at the present time.
Small aqueous droplets on homogeneous surfaces surrounded by a reservoir of vapor are inherently unstable. Depending on the humidity, they keep evaporating and ultimately disappear or grow until they fully wet the surface under supersaturation. We are considering a system departing from this common picture. For nanoscale droplets sitting above hydrophilic patches on a heterogeneous surface, there can exist a range of supersaturated pressures at which the droplets maintain a stable volume, determined by the pertinent contact angle and the size of the patches. The region under the droplet perimeter controls the drop's curvature. Vapor pressure rises along with increased curvature as soon as the drop extends into the hydrophobic area. The drop size may therefore remain stable when its base just covers the hydrophilic patch. The finite range of water−substrate interactions, however, blurs the boundaries between surface regions with different hydrophilicities; hence, the nanodrop contact angle varies with the patch size in a gradual manner. We use molecular simulations to examine this dependence on model surfaces with either chemical or topological heterogeneities. For both types of heterogeneities, our results show the contact angle of a nanodroplet can be predicted by the local Cassie−Baxter mixing relation applied to the area within the interaction range from the drop's perimeter, which, in turn, enables predictions for drop condensation and saturated vapor pressure above partially wetted nanopatterned hydrophilic/hydrophobic surfaces.
Abstract. Neutron diffraction measurements for D 2 O in SBA-15 silica of pore diameter 86Å have been made in a temperature range from 300 K to 100 K. The pore-filling factor for the liquid phase is 0.95, resulting in an 'almost-filled' sample. The nucleation and transformation of the ice phase was determined for cooling and warming cycles at two different rates. The primary nucleation event at 258 K leads to a defective form of ice-I with predominantly cubic ice features. For temperatures below the main nucleation event, the data indicate the formation of an interfacial layer of disordered water/ice that varies with temperature and is reversible. The main diffraction peak for the water phase shows similar features to those observed in earlier studies, indicating enhanced hydrogen-bonding and network correlations for the confined phase as the temperature is decreased. A detailed profile analysis of the triplet-peak is presented in the accompanying Paper 3.
We demonstrate that an all-antiferromagnetic tunnel junction with current perpendicular to the plane geometry can be used as an efficient spintronic device with potential high-frequency operation. By using state-of-the-art density functional theory combined with quantum transport, we show that the Néel vector of the electrodes can be manipulated by spin-transfer torque. This is staggered over the two different magnetic sublattices and can generate dynamics and switching. At the same time the different magnetization states of the junction can be read by standard tunneling magnetoresistance. Calculations are performed for CuMnAs|GaP|CuMnAs junctions with different surface terminations between the antiferromagnetic CuMnAs electrodes and the insulating GaP spacer. We find that the torque remains staggered regardless of the termination, while the magnetoresistance depends on the microscopic details of the interface. DOI: 10.1103/PhysRevB.95.060403Antiferromagnetic (AF) materials are magnetically ordered compounds where two or more spin sublattices compensate each other, resulting in a vanishing macroscopic magnetization. As a consequence, an antiferromagnet does not produce stray field, and closely separated AF nanostructures are not magnetostatically coupled. In addition, the typical time scale for the dynamics of the antiferromagnetic order parameter, the Néel vector, is set by the AF resonance frequency, which is typically much larger than that of a ferromagnet, and may approach the THz range [1]. It is then not surprising that antiferromagnets have recently received considerable attention as a materials platform for magnetic data storage, logic, and high-frequency applications [2]. One limitation of the AF materials class is the fact that most antiferromagnets are insulators, while often spintronics devices require driving currents through the structure.Recently, metallic CuMnAs has been proposed as a good candidate for AF spintronics applications [3]. Tetragonal CuMnAs is antiferromagnetic at room temperature and can be grown epitaxially on GaP. Furthermore, it has been shown that one can manipulate the Néel vector of CuMnAs thin films by electric current pulses [4]. This is explained as the result of atomically staggered spin-orbit torques (SOTs), 1 which accompany the current flow in antiferromagnets where the global inversion symmetry is broken due to the presence of two spin sublattices forming inversion partners [5]. The reported Néel temperature of CuMnAs is (480 ± 5) K [6], while the lattice parameters of bulk tetragonal CuMnAs are a = b = 3.820Å and c = 6.318Å. According to density functional theory (DFT) calculations, CuMnAs in its AF ground state is metallic, but it has a rather low density of states at the Fermi level [3]. Here, we investigate whether such a unique AF metal can be used in standard magnetic tunnel junctions (MTJs) and demonstrate that these can be written by spin-transfer torques (STTs) and read by standard tunnel magnetoresistance (TMR). * stamenom@tcd.ie 1 These are also referred to ...
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.